高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 338.

• Organometallic Chemistry • 上一篇    下一篇

首例阳离子型茂铁(Ⅰ)富勒辉[C60]衍生物的合成、结构

朱应怀,宋礼成   

  1. Department of Chemistry, Nankai University, Tianjin 300071, China
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 通讯作者: 宋礼成,教授
  • 基金资助:
    国家自然科学基金

Synthesis and Structure of the first cationic ferrocene C60 derivative

Ying-Huai Zhu, Li-Cheng Song   

  1. Department of Chemistry, Nankai University, Tianjin 300071, China
  • Online:1998-12-31 Published:1998-12-31
  • Contact: 宋礼成,教授

摘要: 自富勒烯被宏观量制备以来[1],人们对C60与过渡金属配合物反应性作了广泛研究,已合成出许多C60过渡金属有机物,如(η2-C60)Pt(PPh3)2[2], (η2-C60)Fe(CO)4[3]等。但至今尚未见阳离子型茂铁(Ⅰ)富勒烯衍生物的报道。本文首次通过选择性配体置换方法分离并表征了首例阳离子型茂铁(Ⅰ)富勒烯衍生物[CpFe(CO)2]4+C60[BF4]4-(1)。

关键词: 富勒烯[C60], 阳离子茂铁配合物, 配体置换

Abstract: The first cationic ferrocene C60 derivative[CpFe(CO)2]4+C60[BF4]4- was synthesized by a new route involving substitution of the loose ligand C3H6 by C60 and characterized by EA, 1HNMR, FAB-MS, IR and UV-vis spectrum. The new air-sensitive compound has a D2h symmetry.

Key words: Fullerenc [C60], Cationic ferrocene (Ⅰ) complex compound, Ligand Substitution

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