高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 334.

• Organometallic Chemistry • 上一篇    下一篇

Synthesis and Characterization of Some Novel Organochromium Fullerene-C60 Derivatives

Song Li-Cheng1, Zhu Ying-Huai1, Liu Pong-Chung1, Tian Jian-Guo2, Li Ga2   

  1. 1. Department of Chemistry, Nankai University, Tianjin 300071;
    2. Department of Physics, Nankai University, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    National Natural Science Foundation of China and the Special Foundation of State Education Committee of China for financial support of this project

Synthesis and Characterization of Some Novel Organochromium Fullerene-C60 Derivatives

Song Li-Cheng1, Zhu Ying-Huai1, Liu Pong-Chung1, Tian Jian-Guo2, Li Ga2   

  1. 1. Department of Chemistry, Nankai University, Tianjin 300071;
    2. Department of Physics, Nankai University, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    National Natural Science Foundation of China and the Special Foundation of State Education Committee of China for financial support of this project

PDF (PC)

摘要： Although the organotransition metal fullerene-C60 derivatives have been intensively studied, no report regarding organochromium complexes containing a direct chromium to C60 bond has appeared in literatures.1 Now, we report preliminarily the synthesis, characterization and properties of the first such chromium complexes, namely single isomer fac-Cr(CO)3(dppe)(η2-C60) and the isomer mixture of fac- and mer-Cr(CO)3(dppe)(η2-C60).

Abstract: Although the organotransition metal fullerene-C60 derivatives have been intensively studied, no report regarding organochromium complexes containing a direct chromium to C60 bond has appeared in literatures.1 Now, we report preliminarily the synthesis, characterization and properties of the first such chromium complexes, namely single isomer fac-Cr(CO)3(dppe)(η2-C60) and the isomer mixture of fac- and mer-Cr(CO)3(dppe)(η2-C60).

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