高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 330.

• Organometallic Chemistry • 上一篇    下一篇

Effect of Axial Ligands on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex

CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project 29472055 supported by National Natural Science Foundation of China

Effect of Axial Ligands on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex

CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project 29472055 supported by National Natural Science Foundation of China

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摘要： There are many dimetalloenzymes in nature[1]. To mimic these enzymes, we synthesized a new dimanganese Schiff base complex-Bis[N,N'-ethylene-2,2,-(phenylmethylene)-bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese Mn2L (shown in Fig.1). Its structure was confirmed by IR, UV-Vis, 1HNMR and elemental analysis. It can catalyze monooxygenation of cyclohexane with PhIO as an oxidant.

Abstract: There are many dimetalloenzymes in nature[1]. To mimic these enzymes, we synthesized a new dimanganese Schiff base complex-Bis[N,N'-ethylene-2,2,-(phenylmethylene)-bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese Mn2L (shown in Fig.1). Its structure was confirmed by IR, UV-Vis, 1HNMR and elemental analysis. It can catalyze monooxygenation of cyclohexane with PhIO as an oxidant.

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