高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 281.

• Organic Synthesis Chemistry • 上一篇    下一篇

Studies on the Bicyclolphosphite of Saccharides

Cao Linghua1, Sun Guanzhong2, Liu Yuting1   

  1. 1. Department of Chemistry, Xinjiang University, Urumqi 830046;
    2. Department of Chemistry, Tianjin Medical University, Tianjin 300070
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project supported by National Natural Science Foundation of China

Studies on the Bicyclolphosphite of Saccharides

Cao Linghua1, Sun Guanzhong2, Liu Yuting1   

  1. 1. Department of Chemistry, Xinjiang University, Urumqi 830046;
    2. Department of Chemistry, Tianjin Medical University, Tianjin 300070
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project supported by National Natural Science Foundation of China

PDF (PC)

摘要： Bicyclophosphitication of saccharide was used for synthesis of optically active organic phosphor compounds widely. The sugars contained phosphite ring are the inductor in stereochemistry. The nucleophilic subsitution on tetrahedron-phosphor atom is provided with specific stereo-direction. These compounds, with highly stereoselectivity, and can be used as the highly selectivity reagent for organic reactions.

Abstract: Bicyclophosphitication of saccharide was used for synthesis of optically active organic phosphor compounds widely. The sugars contained phosphite ring are the inductor in stereochemistry. The nucleophilic subsitution on tetrahedron-phosphor atom is provided with specific stereo-direction. These compounds, with highly stereoselectivity, and can be used as the highly selectivity reagent for organic reactions.

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