高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 271.

• Organic Synthesis Chemistry • 上一篇    下一篇

Study on the Reaction of Tricovalent Chlorophosphines with Aldehydes Containing Withdrawing Electron Groups

Liang Nian HE1,2, Ren Xi ZHUO1   

  1. 1. Department of Chemistry, Laboratory of Biomedical Polymer Materials of the State Education Commission of China, Wuhan University, Wuhan 430072;
    2. Institute of Organic Synthesis, Central China Normal University, Wuhan 430079
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    This project was supported by the Natural Science Foundation of Hubei Province and the Dawn Plan of Science and Technology for Scientists of Wuhan City

Study on the Reaction of Tricovalent Chlorophosphines with Aldehydes Containing Withdrawing Electron Groups

Liang Nian HE1,2, Ren Xi ZHUO1   

  1. 1. Department of Chemistry, Laboratory of Biomedical Polymer Materials of the State Education Commission of China, Wuhan University, Wuhan 430072;
    2. Institute of Organic Synthesis, Central China Normal University, Wuhan 430079
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    This project was supported by the Natural Science Foundation of Hubei Province and the Dawn Plan of Science and Technology for Scientists of Wuhan City

PDF (PC)

摘要： α-Polychloroalkyl phosphoric dichlorides and their derivatives 2,3,4 has insecticidal activity1-4 and may be used as an intermediate to make other insecticides by reaction with alcohol, phenol, thiophenol or mercaptan. They can be prepared by various conventional methods of preparing phosphorus thioesters. Here we wish to report the addition reaction of tricovalent chlorophosphines with aldehydes containing withdrawing electron groups and its application in preparing of polychloroalkyl phosphorus dichlorides and their derivatives. The process can be represented by the following equation.

Abstract: α-Polychloroalkyl phosphoric dichlorides and their derivatives 2,3,4 has insecticidal activity1-4 and may be used as an intermediate to make other insecticides by reaction with alcohol, phenol, thiophenol or mercaptan. They can be prepared by various conventional methods of preparing phosphorus thioesters. Here we wish to report the addition reaction of tricovalent chlorophosphines with aldehydes containing withdrawing electron groups and its application in preparing of polychloroalkyl phosphorus dichlorides and their derivatives. The process can be represented by the following equation.

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