高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 121.

• Organic Synthesis Chemistry • 上一篇    下一篇

STUDIES ON SULFINATODEHALOGENATION:THE REACTION OF POLYFLUOROALKYL IODIDES WITH 4-PENTENOIC ACID COMPOUNDS

WU Fan-Hong1, HUANG Wei-Yuan2   

  1. 1. Department of Organic Chemistry, Institute of Fundamental Education, East China University of Science and Technology, Shanghai 200237 China;
    2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • 出版日期:1998-12-31 发布日期:1998-12-31

STUDIES ON SULFINATODEHALOGENATION:THE REACTION OF POLYFLUOROALKYL IODIDES WITH 4-PENTENOIC ACID COMPOUNDS

WU Fan-Hong1, HUANG Wei-Yuan2   

  1. 1. Department of Organic Chemistry, Institute of Fundamental Education, East China University of Science and Technology, Shanghai 200237 China;
    2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Online:1998-12-31 Published:1998-12-31

摘要: The radical addition of polyfluoroalkyl iodides to carbon-carbon multiple bonds is one of the most important and general methods for synthesis of a variety of fluorine-containing organic compounds.[1] Studies in our laboratory on stulfinatodehalogenation reaction showed that sodium dithionite was a excellent initiation reagent for the addition of polyfluoroalkyl iodides, bromides and halocarbons to alkenes, alkynes and conjugated dienes effectively under mild conditions.[2]

Abstract: The radical addition of polyfluoroalkyl iodides to carbon-carbon multiple bonds is one of the most important and general methods for synthesis of a variety of fluorine-containing organic compounds.[1] Studies in our laboratory on stulfinatodehalogenation reaction showed that sodium dithionite was a excellent initiation reagent for the addition of polyfluoroalkyl iodides, bromides and halocarbons to alkenes, alkynes and conjugated dienes effectively under mild conditions.[2]

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