多尺度柔性结构的防覆冰性能

doi:10.7503/cjcu20150248

高等学校化学学报 ›› 2015, Vol. 36 ›› Issue (8): 1548.doi: 10.7503/cjcu20150248

多尺度柔性结构的防覆冰性能

王磊, 侯永平, 郑咏梅()

北京航空航天大学化学与环境学院, 北京 100191

收稿日期:2015-03-30 出版日期:2015-08-10 发布日期:2015-06-30
作者简介:联系人简介: 郑咏梅, 女, 博士, 教授, 博士生导师, 主要从事仿生表面的各向异性及浸润性材料研究. E-mail:zhengym@buaa.edu.cn
基金资助:
国家自然科学基金(批准号: 21234001, 21473007)和国家教育部博士点专项基金(批准号: 20121102110035)资助

Icephobic Property on Multiscale Flexible Structures^†

WANG Lei, HOU Yongping, ZHENG Yongmei^*()

School of Chemistry and Environment, Beihang University, Beijing 100191, China

Received:2015-03-30 Online:2015-08-10 Published:2015-06-30
Contact: ZHENG Yongmei E-mail:zhengym@buaa.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.21234001, 21473007) and the Doctoral Fund of Ministry of Education of China(No.20121102110035)

摘要/Abstract

摘要：

通过软复型和晶体生长的方法制备了具有柔性微米锯齿和纳米棒结构的微纳米复合表面, 其具有低温低黏附的特性, 达到了优异的防覆冰效果. 柔性微纳米结构表面的形变, 可以在低温条件下有效去除液滴. 研究结果表明, 微米结构的弯曲作用改变了液滴在表面的三相线, 凹面增大了气/液/固三相线长度, 增加了驱动液滴的难度; 凸面减小了气/液/固三相线长度, 有利于减少液滴与表面之间黏附力, 使液滴在重力作用下快速脱除.

关键词: 软复型, 晶体生长, 三相线, 防覆冰, 柔性结构

Abstract:

A kind of soft micro-ratchet/nano-rods structure surface was fabricated by intergrating the methods of soft-lithography and crystal growth, which realized low adhesion and icephobic properties in low temperature environment. The droplet could be driven off before it freezes by the deformation of micro-ratchet. The results indicate that the bend effect changes the three phase contact line and generates droplet-driven performance with different bend angles. The dent effect increases the three phase contact line and increases the difficulty for driving droplet. While, the raised effect decreases the three phase contact line and decreases the adhesion force between liquid and solid, which makes the droplet off the surface easily with the effect of gravity. This special structure has real potential in icephobic field.

Key words: Soft-lithography, Crystal growth, Three phase contact line, Icephobic, Flexible structure

中图分类号:

O647

TrendMD:

王磊, 侯永平, 郑咏梅. 多尺度柔性结构的防覆冰性能. 高等学校化学学报, 2015, 36(8): 1548.

WANG Lei, HOU Yongping, ZHENG Yongmei. Icephobic Property on Multiscale Flexible Structures^†. Chem. J. Chinese Universities, 2015, 36(8): 1548.

图/表 6

Fig.1 SEM images of the surface structure(A, C) Top and side view of microstructures; (B, D) top and side view of nanostructures;(E—G) initial state, dent state and raised state.

Fig.2 Relationship between periodicity and bend angle

Fig.3 Relationship of contact angle and sliding angle(A) and adhesion force(B) with temperature

Fig.4 In situ observation of ice delay time on the surface(A)—(D) The icing and melting processes; (E) the relationship of ice/melt times and ice delay time.

Fig.5 Droplet driven processes in two bend states(A, B) and the relationship of bend angles and ACA/RCA(C)

Fig.6 Droplet driven processes in two bend directions(A, C) and the sketches of driven state in two directions(B, D)

参考文献 17

[1]	Liu Q., Liu N., Feng L., Wei Y., Chem. J. Chinese Universities, 2013, 34(6), 1466—1469
	(刘卿, 刘娜, 冯琳, 危岩. 高等学校化学学报, 2013, 34(6), 1466—1469)
[2]	Jalabert L., Bottier C., Kumemura M., Fujita H., Microelectron Eng., 2010, 87(5—8), 1431—1434
[3]	Mcalpine M. C., Ahmad H., Wang D. W., Heath J. R., Nat. Mater., 2007, 6(5), 379—384
[4]	Hancock M. J., Sekeroglu K., Demirel M. C., Adv. Funct. Mater., 2012, 22(11), 2223—2234
[5]	Hu Y. H., He H. R., Ma Y. M., Yang X. F., Chem. J. Chinese Universities, 2013, 34(2), 295—298
	(胡亚徽, 贺惠蓉, 马养民, 杨秀芳. 高等学校化学学报, 2013, 34(2), 295—298)
[6]	Feng L., Li S., Li Y., Li H., Zhang L., Zhai J., Song Y., Liu B., Jiang L., Zhu D., Adv. Mater., 2002, 14(24), 1857—1860
[7]	Wu Y. W., Hang T., Yu Z., Xu L., Li M., Chem. Commun., 2014, 50(61), 8405—8407
[8]	Jiang L., Zhao Y., Zhai J., Angew. Chem., 2004, 43(33), 4338—4340
[9]	Bixler G. D., Bhushan B., Crit Rev. Solid State, 2015, 40(1), 1—37
[10]	Mei H., Luo D., Guo P., Song C., Liu C., Zheng Y., Jiang L., Soft Matter, 2011, 7(22), 10569—10573
[11]	Guo P., Zheng Y., Wen M., Song C., Lin Y., Jiang L., Adv. Mater., 2012, 24(19), 2642—2648
[12]	Wen M. X., Zheng Y. M., Chem. J. Chinese Universities, 2014, 35(5), 1011—1015
	(文孟喜, 郑咏梅. 高等学校化学学报, 2014, 35(5), 1011—1015)
[13]	Gao L. L., Jones A. K., Sikka V. K., Wu J. Z., Gao D., Langmuir, 2009, 25(21), 12444—12448
[14]	Kulinich S. A., Honda M., Zhu A. L., Rozhin A. G., Du X. W., Soft Matter, 2015, 11(5), 865—861
[15]	Sun M. H., Luo C. X., Xu L. P., Ji H., Qi O. Y., Yu D. P., Chen Y., Langmuir, 2005, 21(19), 8978—8981
[16]	Wu S. Z., Wang J. N., Niu L. G., Yao J., Appl. Phys. Lett., 2011, 98(8), 081902
[17]	Ramachandran R., Sobolew K., Nosonovsky M., Langmuir, 2015, 31(4), 1437—1444

多尺度柔性结构的防覆冰性能

Icephobic Property on Multiscale Flexible Structures^†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 17

相关文章 6

编辑推荐

Metrics

本文评价

[1]	张想, 张雷, 邹玥, 黄新华, 潘成岭, 侯长民, 徐吉庆. Bi₁₂SiO₂₀多级立方块的水热合成、表征及光催化性能[J]. 高等学校化学学报, 2015, 36(12): 2372.
[2]	张志敏, 梁晓娟, 赵斌宇, 陈兆平, 刘炳峰, 钟家松, 向卫东, 吕春燕. Ce,Mn:YAG单晶的生长及光学性能[J]. 高等学校化学学报, 2013, 34(8): 1826.
[3]	吴健, 郑裕东, 高爽, 郭佳, 崔秋艳, 丁寻, 陈晓华. 纳米银在细菌纤维素凝胶膜中的原位合成及性能表征[J]. 高等学校化学学报, 2013, 34(1): 210.
[4]	徐晓虹, 张敏, 吴建锋, 刘淑洁, 方斌正, 冷光辉. 锌片上多形貌ZnO微晶的水热合成及生长机理[J]. 高等学校化学学报, 2011, 32(8): 1703.
[5]	王丰, 刘进元 . 水稻谷胱甘肽磷脂氢过氧化物酶的表达、纯化及晶体生长条件初筛[J]. 高等学校化学学报, 2007, 28(9): 1701.
[6]	叶红勇,赖宏伟,吴淑杰,崔湘浩,阚秋斌,榆正根 . 常温直接沉淀法制备ZnO纳米棒[J]. 高等学校化学学报, 2007, 28(2): 312.

多尺度柔性结构的防覆冰性能

Icephobic Property on Multiscale Flexible Structures†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 17

相关文章 6

编辑推荐

Metrics

本文评价

Icephobic Property on Multiscale Flexible Structures^†