Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (3): 411.

• Articles • Previous Articles     Next Articles

Studies on the Surface Aminopropylsilanized Quartz by Contact Angle Method

KONG Xiang-Xing, ZHANG Xi, GAO Mang-Lai, SHEN Jia-Cong   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1993-05-04 Revised:1993-09-23 Online:1994-03-24 Published:1994-03-24

Abstract: In this paper,the concentration of amino group onto aminopropylsilanized(APS)quartz was measured by using contact angle method.Using phenol as a probe, the weak acid (phenol in CH2I2 solution)/the base(APSquartz) adsorption was studied in detail, and the surface concentration of amino group on APSsurface was calculaled as 1.14 nm2/mole when the Langmuir isotherm was used.And further ,SAzoNC6OH acted as a probe, the surface adsorption concentration and molecular section area was indetified by using UV-visible absorption spectra.Comparing the area of per amino group of 0.41 nm2 from adsorption spectra measurement, a densed packing model, with hydrogen bonding existing between amino groups, was proposed.

Key words: Monomolecular layer, Contact angle, Langmuir isotherm adsorption

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