Chem. J. Chinese Universities

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Synthesis and Characterization of Hyperbranched Poly(β-cyclodextrin)

TIAN Wei, FAN Xiao-Dong*, JIANG Min, DING Wen-Xiu, WANG Hao, LIU Yu-Yang   

  1. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi′an 710072, China
  • Received:2007-08-14 Revised:1900-01-01 Online:2008-01-10 Published:2008-01-10
  • Contact: FAN Xiao-Dong

Abstract: Hyperbranched poly(β-cyclodextrin) was successfully prepared via hydrosilylation from ABx type cyclodextrin monomer. The molecular structures of ABx monomer and hyperbranched polymer were characterized with 1H NMR, 13C NMR, 29Si NMR, MALDI-TOF MS and elemental analysis. In addition, molecular weight, molecular weight distribution(MWD) and intrinsic viscosity of hyperbranched polymer were obtained via size exclusion chromatography/multi-angle laser light scattering(SEC/MALLS) technology.

Key words: ABx type cyclodextrin monomer, Hyperbranched polymer, Hyperbranched poly(β-cyclodextrin), Hydrosilylation

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