Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (1): 6.
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JI Tian-Hao, MENG Xian-Ping, WU Nian-Zu, LI Shi-Jie, LIU Ying-Jun
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Abstract: The palladium cluster encaged in Y-type zeolite has been synthesized by the method of microwave radiation ion exchange-hydrogen reduction with [Pd (NH3)4](NO3)2.H2Oas precursor of ion exchange.The results of XRDand XPSshow that calcination tem-perature has an important influence on the Pd atoms encaging into zeolite NaYand the for-mation of Pd clusters.When the Pd content in zeolite Yis 6.13%, Pd can be also encaged in zeolite Yand form cluster under the condition of preparation at 240 Cof calcination temper-ature and 210 Cof reduction temperature.Using the sample of Pd content 0.410% obtained under the same conditions, the conversion on COcomplete oxidation is 100% at room tem-perature and at 2000 h-1 (space velocity).Therefor, Pd cluster encaged Y-type zeolite is an excellent catalyst for complete oxidation of carbon monoxide.
Key words: Pd cluster, Y-type zeolite, CO complete oxidation catalyst
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JI Tian-Hao, MENG Xian-Ping, WU Nian-Zu, LI Shi-Jie, LIU Ying-Jun. The Synthesis and Catalytic Performance of Pd Cluster Encaged in Y-type Zeolite[J]. Chem. J. Chinese Universities, 1997, 18(1): 6.
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