Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (1): 6.

• Articles • Previous Articles     Next Articles

The Synthesis and Catalytic Performance of Pd Cluster Encaged in Y-type Zeolite

JI Tian-Hao, MENG Xian-Ping, WU Nian-Zu, LI Shi-Jie, LIU Ying-Jun   

  1. Institute of Physical Chemistry, Peking University, Beijing, 100871
  • Received:1996-01-30 Online:1997-01-24 Published:1997-01-24

Abstract: The palladium cluster encaged in Y-type zeolite has been synthesized by the method of microwave radiation ion exchange-hydrogen reduction with [Pd (NH3)4](NO3)2.H2Oas precursor of ion exchange.The results of XRDand XPSshow that calcination tem-perature has an important influence on the Pd atoms encaging into zeolite NaYand the for-mation of Pd clusters.When the Pd content in zeolite Yis 6.13%, Pd can be also encaged in zeolite Yand form cluster under the condition of preparation at 240 Cof calcination temper-ature and 210 Cof reduction temperature.Using the sample of Pd content 0.410% obtained under the same conditions, the conversion on COcomplete oxidation is 100% at room tem-perature and at 2000 h-1 (space velocity).Therefor, Pd cluster encaged Y-type zeolite is an excellent catalyst for complete oxidation of carbon monoxide.

Key words: Pd cluster, Y-type zeolite, CO complete oxidation catalyst

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