Preparation of Poly(styrene-co-4-vinylpyridine)/Silica Nanoscale Hybrids Supported Cyclopentadienyltitanium Trichloride(CpTiCl3) Catalyst and Styrene Polymerization

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (12): 2117.

• Articles • Previous Articles Next Articles

Preparation of Poly(styrene-co-4-vinylpyridine)/Silica Nanoscale Hybrids Supported Cyclopentadienyltitanium Trichloride(CpTiCl₃) Catalyst and Styrene Polymerization

ZHU Ning^1,2, TANG Tao¹, CUI DongMei^1,3, FENG ZhiLiu¹, HUANG BaoTong¹

1. State Key Laboratoryof Polymer Physicsand Chemistry, Changchun Instituteof Applied Chemistry, Polymer Chemistry United Laboratory, Chinese Academy of Sciencesand China Petro-chemical Corporation, Chinese Academy of Sciences, Changchun 130022, China;
2. Departmentof Chemistry, Northeastern University, Shenyang 110006, China;
3. Department of Chemical Engineering, Jilin Institute of Technology, Changchun 130012, China

Received:2000-09-21 Online:2001-12-24 Published:2001-12-24

Abstract

Abstract: To obtain a novel support with practical value for metallocene catalyst(ηC₅H₅)TiCl₃(CpTiCl₃), poly(styrene-co-4-vinyl-pyridine)/SiO₂ nanoscale hybrid material(SrP/SiO₂) was firstly produced as support. After pretreatment by methylaluminoxane(MAO), the hybrid materials reacted with CpTiCl₃. The results from SAXS, SEMand TEMindicated the morphology and structure of organic/inorganic hybrid materials, and the size of inorganic particle in hybrid was nanoscale. The results from IRand XPS-showed that there were two possible cationic active species in the hybridsupported catalyst, the polymerization results of styrene proved this possibility.

Key words: Stryrene4vinylpyridine) copolymer, Organicinorganic hybrids, Cyclopentadienyltitanium trichloride, Support

CLC Number:

TrendMD:

ZHU Ning, TANG Tao, CUI DongMei, FENG ZhiLiu, HUANG BaoTong . Preparation of Poly(styrene-co-4-vinylpyridine)/Silica Nanoscale Hybrids Supported Cyclopentadienyltitanium Trichloride(CpTiCl₃) Catalyst and Styrene Polymerization[J]. Chem. J. Chinese Universities, 2001, 22(12): 2117.

[1]	REN Shijie, QIAO Sicong, LIU Chongjing, ZHANG Wenhua, SONG Li. Synchrotron Radiation X-Ray Absorption Spectroscopy Research Progress on Platinum Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220466.
[2]	ZHOU Leilei, CHENG Haiyang, ZHAO Fengyu. Research Progress of CO₂ Hydrogenation over Pd-based Heterogeneous Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220279.
[3]	WU Jun, HE Guanchao, FEI Huilong. Self-supported Film Electrodes Decorated with Single Atoms for Energy Electrocatalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220051.
[4]	HU Huimin, CUI Jing, LIU Dandan, SONG Jiaxin, ZHANG Ning, FAN Xiaoqiang, ZHAO Zhen, KONG Lian, XIAO Xia, XIE Zean. Influence of Different Transition Metal Decoration on the Propane Dehydrogenation Performance over Pt/M-DMSN Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210815.
[5]	LI Xueyu, WANG Zhao, CHEN Ya, LI Keke, LI Jianquan, JIN Shunjing, CHEN Lihua, SU Baolian. Enhanced Catalytic Performance of Supported Nano-gold by the Localized Surface Plasmon Resonance for Selective Hydrogenation of Butadiene [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220174.
[6]	JIANG Shan, SHEN Qianqian, LI Qi, JIA Husheng, XUE Jinbo. Pd-loaded Defective TiO₂ Nanotube Arrays for Enhanced Photocatalytic Hydrogen Production Performance [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220206.
[7]	LI Haibo, XIAO Changfa, JIANG Long, HUANG Yun, DAN Yi. Copolymerization of Methyl Acrylate and 1-Octene Catalyzed by the Loaded Aluminum Chloride on MCM-41 Molecular Sieve [J]. Chem. J. Chinese Universities, 2021, 42(9): 2974.
[8]	HUANG Pai, ZHOU Guangyuan, LIU Bo, WANG Lei, ZHANG Jiaqi. Support Effect of Nanosized Hierarchical Silicalite-1 Zeolite on the Properties of Ziegler-Natta Catalyzed Polypropylene [J]. Chem. J. Chinese Universities, 2020, 41(9): 2025.
[9]	LI Xiaoli, HUANG Liang, DUAN Hongjuan, ZHANG Li, ZHANG Haijun. Preparation and Catalytic Activity of Graphene Supported Pt/Co Nanoparticles for Hydrogen Generation from KBH₄ [J]. Chem. J. Chinese Universities, 2019, 40(8): 1662.
[10]	Xiaoyu FAN,Ke WANG,Shiyong SUN,Biaobiao MA,Rui LÜ. Construction and Catalytic Performances of Fe-aminoclay Nanostructured Lipase ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2512.
[11]	CHEN Weimin, ZHU Zhenyu. Performances of a Hybrid Carbon Material Supported Pd Catalyst for Ethanol Electrooxidation^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 337.
[12]	YU Tian, XU Chengnan, YU Yuan, ZHAO Feifei, PAN Yiting, LIU Cai, HUANG Yongdong, ZHANG Rongyue. Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1740.
[13]	TENG Xiaobo,ZHANG Chunxia,ZHANG Ying. Synthesis of the Supported Au Polystyrene/poly(acrylic acid) Composite Microspheres and Their pH Regulated Performance^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1509.
[14]	LIU Jiaxin, SONG Yian, HUANG Yudong. PdZn Alloy Nanoparticles Epitaxial Growth on ZnO Nanowires for Methanol Steam Reforming^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1372.
[15]	ZHOU Wenjun, ZHOU Yu, ZHANG Xiazhong, ZENG Bin. Preparation and Suzuki Reaction Performance of Pectin-supported Palladium Catalyst^† [J]. Chem. J. Chinese Universities, 2016, 37(4): 669.

Preparation of Poly(styrene-co-4-vinylpyridine)/Silica Nanoscale Hybrids Supported Cyclopentadienyltitanium Trichloride(CpTiCl₃) Catalyst and Styrene Polymerization

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments