Synthesis and X-ray Diffraction Crystal Structure ofBis(trialkyltin) 1, 1'-ferrocene Dicarboxylates

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (4): 581.

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Synthesis and X-ray Diffraction Crystal Structure ofBis(trialkyltin) 1, 1'-ferrocene Dicarboxylates

MU Zhao-De¹, SUN Li-Juan², LUO Ning¹, XIE Qing-Lan²

1. Institute of Pharmaceutical Chemistry and Biomaterials, Chongqing University of Medical Sciences, Chongqing 400016 China;
2. National Key Laboraatory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Received:2000-12-27 Online:2002-04-24 Published:2002-04-24

Abstract

Abstract: Thirteen new bis(trialkyl)tin 1, 1' -ferrocene dicarboxylates were synthesised and characterizedby IR, ¹H NMR, MSand elemental analysis.The X-ray diffraction crystal structure ofMeCy₂SnO₂CC₅H₄FeC₅H₄CO₂SnCy₂Me was determined.The results show that the Sn atom is in slighlydistorted trigonal-bipyrimidal environment.The compound has a linear polymer's structure.

Key words: Trialkyltin, Ferrocene dicarboxylate, Spectrascopic characterization, X-ray diffraction crystal structure

CLC Number:

O621.3

TrendMD:

MU Zhao-De, SUN Li-Juan, LUO Ning, XIE Qing-Lan. Synthesis and X-ray Diffraction Crystal Structure ofBis(trialkyltin) 1, 1'-ferrocene Dicarboxylates[J]. Chem. J. Chinese Universities, 2002, 23(4): 581.

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Synthesis and X-ray Diffraction Crystal Structure ofBis(trialkyltin) 1, 1'-ferrocene Dicarboxylates

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