Thermodynamic Study of Coordination of Meso-substituted Iron(Ⅲ)Tetraporphyrin with Substituted Imidazoles

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (10): 1608.

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Thermodynamic Study of Coordination of Meso-substituted Iron(Ⅲ)Tetraporphyrin with Substituted Imidazoles

CHEN Hong-Wei, ZHU Zhi-Ang, RUAN Wen-Juan, CHEN Zheng-Hua, ZHANG Zhi-Hui, CHEN Rong-Ti

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1995-10-18 Online:1996-10-24 Published:1996-10-24

Abstract

Abstract: The thermodynamics of axial coordination reaction of Fe(Ⅲ)T(m-X)PPCl(X=—CH₃,—H,—OCH₃,—Cl,—NO₂)with ligands of the substituted imidazole(L=Im(imidazole),2-Melm(2-methylimidazole),GMZ(clotrimidazole),at different temperature in DMSOhave been studied.

Key words: Meso-substituted tetraphenylporphinatoiron(Ⅲ)(Fe(Ⅲ)T(m-X)PPCl), Substituted imidazole, Visible spectra, Equilibrium constants, Coordination reaction

TrendMD:

CHEN Hong-Wei, ZHU Zhi-Ang, RUAN Wen-Juan, CHEN Zheng-Hua, ZHANG Zhi-Hui, CHEN Rong-Ti. Thermodynamic Study of Coordination of Meso-substituted Iron(Ⅲ)Tetraporphyrin with Substituted Imidazoles[J]. Chem. J. Chinese Universities, 1996, 17(10): 1608.

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Thermodynamic Study of Coordination of Meso-substituted Iron(Ⅲ)Tetraporphyrin with Substituted Imidazoles

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