Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (9): 1433.

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The 151Eu Mossbauer Study for Double Perovskite REEuCr2O6

LI Li-ping1, KANG Zhi-Jian2, WEI Quan3, SU Wen-Hui1   

  1. 1. Department of Physics, Jilin University, Changchun, 130023;
    2. Department of Chemistry, Jilin University, Changchun, 130023;
    3. Center for Analysis and Measurement, Jilin University, Changchun, 130023
  • Received:1995-08-07 Online:1996-09-24 Published:1996-09-24

Abstract: Double perovskite oxides REEuCr2O6(RE=La, Pr, Nd, Sm, Gd ,Tb ,Dy, Ho,Er, Tm)were prepared by solid state reaction method.The measurement of XRD, IRand 151Eu Mössbauer spectra show that all samples are orthorhombic structure; as the atomic number of REincreases, the cell volumes decrease.The relationship between isomer shift and Vis linear,Quadrupole splits are negative,and with atomic number of REincreasing,their absolute values increase.

Key words: Double perovskite oxide, REEuCr2O6, 151Eu Mö, ssbauer spectrum, Isomer shift

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