Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (4): 587.

• Articles • Previous Articles     Next Articles

A Stereoselective Reductive Rearrangement of Allylic Epoxyalcohols New Synthetic Method of 1,3-Diol

TU Yong-Qiang, XIA Wu-Jiong, WANG Ping-Zhen, ZHAI Jian-Jun, CHEN Yao-Zu   

  1. Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000
  • Received:1998-05-02 Online:1999-04-24 Published:1999-04-24

Abstract: Anovel method for synthesis of stereoselective 1,3-diol from hydroxyepoxides was developed by reductive rearrangement with aluminum isopropoxide, which is very convenient and efficient. The substituted effect and stereochemistry were also discussed.

Key words: Epoxyalcohols, Rearrangement, Stereoselective

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