Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (1): 74.
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FU Bin, ZHAO Chen, ZHANG Pang
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Abstract: Dihydro-9,9,10,10-bis(propiono-γ-lactono)-phenanthrene was synthesized by five steps of reaction with an overall yield of 24%, 7% better than Dallacker synthesis in eight steps. Ethyl 3-(o-iodobenzoyl)propionate was also synthesized from o-iodobenzoyl chloride and triethyl ethane-1,1,2-tricarboxylate in two steps of reaction with an overall yield of 43%, 13% better than the above synthesis. The acylation of triethyl ethane-1,1,2-tri-carboxylate by diphenoyl chloride was also studied and reasonably good yields obtained.
Key words: Dihydrophenanthrenebislactone, Perylenequinone, McMurry reaction
CLC Number:
O629
TrendMD:
FU Bin, ZHAO Chen, ZHANG Pang . A Facile Synthesis of Dallacker Bislactone[J]. Chem. J. Chinese Universities, 2000, 21(1): 74.
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http://www.cjcu.jlu.edu.cn/EN/Y2000/V21/I1/74