Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (1): 1.

• Letters • Previous Articles     Next Articles

  

  1. Key Laboratory of Green Chemistry & Technology,  Ministry of Education, College of Chemistry,  Sichuan University, Chengdu 610064,  China
  • Received:2010-08-17 Revised:2010-11-22 Online:2011-01-10 Published:2010-12-11
  • Contact: GONG Mao-Chu E-mail:nic7501@scu.edu.cn
  • Supported by:

    National Natural Science Foundation of China;National Natural Science Foundation of China

Abstract: CeO2-ZrO2-La2O3-Al2O3(CZLA)samples with different CeO2, ZrO2 and La2O3 contents were prepared by peptizing method. The CZLA samples were characterized by X-ray diffraction (XRD) and N2 adsorption-desorption. The low Pt-Rh content catalysts were prepared by using OSM(Ce0.4Zr0.4Y0.1La0.1O1.9)and CZLA samples as the support, and the catalytic performance was investigated. N2 adsorption-desorption results showed that CZLA sample with 2% La2O3 maintained a highest specific surface area of 97.10 m2?g-1 when aged at 1100℃ for 5 h. After calcination at 1000℃ for 5h, XRD results revealed that both CZLA samples were γ-alumina, lanthanum existed in a dispersed phase, while CZ existed as solid solution in alumina. Activity tests showed that the catalyst which supported by CZLA sample with 2% La2O3 showed an excellent catalytic performance. Its light-off temperature was 249oC, and full conversion temperature was 286oC for C3H8.

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