Electrochemical Properties of  Films of C60  Derivative Modified with  Crown Ether

Chem. J. Chinese Universities ›› 2006, Vol. 27 ›› Issue (3): 498.

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Electrochemical Properties of Films of C₆₀ Derivative Modified with Crown Ether

ZHANG Hua¹,NING Bin¹,WU Yue-Qin¹,FAN Lou-Zhen^1*,GUO Zhi-Xin²

1. Department of Chemistry,Beijing Normal University,Beijing 100875,China;
2. Department of Chemistry,People′s University of China,Beijing 100082,China

Received:2005-04-20 Online:2006-03-10 Published:2006-03-10

Abstract

Abstract:

The electrochemical properties of dibenzo-18-crown-6-C60(DBCFP) films were studied by simultaneous cyclic voltammetry and electrochemical quartz crystal microbalance(EQCM) in acetonitrile solutions containing different supporting electrolytes. The electrochemical properties and the stability of DBCFP film were much different from that of C60 film due to the 18-crown-6 group with large size and soft property. For the sake of comparison,the electrochemical properties of another C₆₀derivative(PSF) with rigid perylene group were also investigated. A mechanism for electrochemical process of DBCFP film in TAB⁺ solution was proposed.

Key words: null

CLC Number:

O646

TrendMD:

ZHANG Hua, NING Bin, WU Yue-Qin, FAN Lou-Zhen, GUO Zhi-Xin. Electrochemical Properties of Films of C₆₀ Derivative Modified with Crown Ether[J]. Chem. J. Chinese Universities, 2006, 27(3): 498.

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Electrochemical Properties of Films of C₆₀ Derivative Modified with Crown Ether

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