Photoluminescence Property of Layered Double Hydroxide Composite with Fluorescein and Detection Towards Fe3+†

doi:10.7503/cjcu20180873

Abstract

Abstract:

FLN/OS-LDH composite(FLN is fluorescein, OS is 1-octane sulfonic acid sodium, and LDH is MgAl layered double hydroxide) was synthesized via ion-exchange method and the photoluminescence and detection for Fe(Ⅲ) was tested. In solid state, the FLN/OS-LDH composite displayed yellowish green emission(565 nm) arising from organic FLN. In formamide(FM), the FLN/OS-LDH can be feasily delaminated into colloidal suspention, and showed blue-shifted green emission(ca. 531 nm). The recognition ability of the FLN/OS-LDH for metal cations was researched. The delaminated FLN/OS-LDH colloid in formamide exhibited high selectivity for Fe³⁺ over other ions(Mg²⁺, Ni²⁺, Co²⁺, Cu²⁺, Zn²⁺, Mn²⁺, Pb²⁺, Cd²⁺, and Hg²⁺) with obvious fluorescence quenching, which can work as a kind of effective fluorescence sensor for detection of Fe³⁺. The detection limit of Fe³⁺ is determined to be 1.27×10^-7 mol/L and the quenching constant(K_sv) is 3.44×10² L/mol.

Key words: Fluorescein, Layered double hydroxide(LDH), Fluorescence chemosensor, Detection of Fe³⁺

CLC Number:

O614

TrendMD:

LIANG Zupei, SU Feifei, GUO Rong, TANG Yuyao, JIN Shuo, YU Zihuan, LI Jian, MA Shulan. Photoluminescence Property of Layered Double Hydroxide Composite with Fluorescein and Detection Towards F $e 3 + †$ [J]. Chem. J. Chinese Universities, 2019, 40(7): 1352.

Figures/Tables 9

Fig.1 Arrangements of gallery species in NO3-LDH precursor(A) and FLN0.02/OS0.98-LDH composite(B)

Fig.2 XRD patterns of NO3-LDH precursor(a) and FLN/OS-LDH composite(b)The d-values are given in nanometers. Inset is the partial enlarged curve b.

Fig.3 FTIR spectra of FLN-Na(a), OS(b), NO3-LDH(c) and FLN/OS-LDH composite(d)

Fig.4 SEM images of precursor NO3-LDH(A) and FLN/OS-LDH composite(B)

Fig.5 Emission spectra of FLN-Na(a)and FLN/OS-LDH composite(b) in solid state(λex = 510 nm)

Fig.6 Emission spectra of FLN-Na(a) and delaminated FLN/OS-LDH(b) in FMa. λex=460 nm, 0.05 g FLN-Na dissolved in 20 mL FM; b. λex=460 nm, 0.05 g FLN/OS-LDH was dispersed in 20 mL FM.

Fig.7 Emission spectra of FLN/OS-LDH colloid mixed with various metal ionsλex = 460 nm.

Fig.8 Emission spectra of FLN/OS-LDH in FM with addition of 0.018—18 mmol/L Fe3+

Fig.9 Plot of I0/I dependence(0—0.4 mmol/L) on Fe3+ concentration of FLN/OS-LDH colloid in FM at 524 nm emission

References 52

[1]	Jayaraj M. K., Vallabhan C. P. G., J. Electrochem. Soc., 1991, 138(5), 1512—1516
[2]	Klemkaite K., Prosycevas I., Taraskevicius R., Khinsky A., Kareiva A., Cent. Eur. J. Chem., 2011, 9(2), 275—282
[3]	Klemkaite K., Khinsky A., Kareiva A., Mater. Lett., 2011, 65(2), 388—391
[4]	Wu J., Ren Z. Y., Du S. C., Kong L. J., Liu B. W.,Xi W., Zhu J. Q., Fu H. G., Nano Res., 2016, 9(3), 713—725
[5]	Miyata S., Clay Clay Min., 1983, 31(4), 305—311
[6]	Newman S. P., Jones W., New J. Chem., 1998, 22(2), 105—115
[7]	Jaubertie C., Holgado M. J., San Roman M. S.,Rives V., Chem. Mat., 2006, 18(13), 3114—3121
[8]	Klemkaite-Ramanauske K., Zilinskas A., Taraskevicius R., Khinsky A., Kareiva A., Polyhedron, 2014, 68, 340—345
[9]	Kuwahara Y., Tamagawa S., Fujitani T., Yamashita H., Bull. Chem. Soc. Jpn., 2016, 89(4), 472—480
[10]	Salak A. N., Tedim J., Kuznetsova A. I., Ribeiro J. L.,Vieira L. G., Zheludkevich M. L., Ferreira M. G. S., Chem. Phys., 2012, 397, 102—108
[11]	Carneiro J., Caetano A. F., Kuznetsova A., Maia F., Salak A. N.,Tedim J., Scharnagl N., Zheludkevich M. L., Ferreira M. G. S., RSC Adv., 2015, 5(50), 39916—39929
[12]	Li H.J., Su X. Y., Bai C. H., Xu Y. Q., Pei Z. C., Sun S. G., Sens. Actuator B-Chem., 2016, 225, 109—114
[13]	Lu P., Liang S., Qiu L., Gao Y. S., Wang Q., J. Membr. Sci., 2016, 504, 196—205
[14]	Serdechnova M., Salak A.N., Barbosa F. S., Vieira D. E. L., Tedim J., Zheludkevich M. L., Ferreira M. G. S., J. Solid State Chem., 2016, 233, 158—165
[15]	Jiang Y., Song Y., Li Y., Tian W., Pan Z., Yang P., Li Y., Gu Q., Hu L., ACS Appl.Mater. Interfaces, 2017, 9(43), 37645—37654
[16]	Hu Z. Q., Chen G. M., Adv. Mater., 2014, 26(34), 5950—5956
[17]	Liu J., Chen G. M., Yang J. P., Polymer, 2008, 49(18), 3923—3927
[18]	Binnemans K., Chem. Rev., 2009, 109(9), 4283—4374
[19]	Gunawan P., Xu R., J. Phys. Chem. C, 2009, 113(39), 17206—17214
[20]	Zhang Z., Chen G. M., Liu J. G., RSC Adv., 2014, 4(16), 7991—7997
[21]	Pan Z., Jiang Y., Yang P., Wu Z., Tian W., Liu L., Song Y., Gu Q., Sun D., Hu L., ACS Nano, 2018, 12(3), 2968—2979
[22]	D’Autreaux B., Tucker N. P., Dixon R., Spiro S., Nature, 2005, 437(7059), 769—772
[23]	Lee J. W., Helmann J. D., Nature, 2006, 440(7082), 363—367
[24]	Weinberg E.D., Eur. J. Cancer Prev., 1996, 5(1), 19—36
[25]	Swaminathan S., Fonseca V.A., Alam M. G., Shah S. V., Diabetes Care, 2007, 30(7), 1926—1933
[26]	Narayanaswamy N., Govindaraju T., Sens. Actuator B-Chem., 2012, 161(1), 304—310
[27]	Hu Z. Q., Wang X. M., Feng Y. C., Ding L.,Li M., Lin C. S., Chem. Commun., 2011, 47(5), 1622—1624
[28]	Huang J. H., Xu Y. F.,Qian X. H., Dalton Trans., 2014, 43(16), 5983—5989
[29]	Kikkeri R., Traboulsi H., Humbert N., Gumienna-Kontecka E., Arad-Yellin R., Melman G., Elhabiri M., Albrecht-Gary A. M., Shanzer A., Inorg. Chem., 2007, 46(7), 2485—2497
[30]	Weizman H., Ardon O., Mester B., Libman J., Dwir O., Hadar Y., Chen Y., Shanzer A., J. Am. Chem. Soc., 1996, 118(49), 12368—12375
[31]	Li Z., Zhou Y., Yin K., Yu Z., Li Y., Ren J., Dyes Pigment, 2014, 105, 7—11
[32]	Yang Y.T., Huo F. J., Yin C. X., Chao J. B., Zhang Y. B., Dyes Pigment, 2015, 114, 105—109
[33]	Fan C. H. Huang X. M., Han L. H., Lu Z. L., Wang Z., Yi Y. P., Sens. Actuator B-Chem., 2016, 224, 592—599
[34]	Li P., Zhang M., Sun X. K., Guan S. W., Zhang G., Baumgarten M.,Mullen K., Biosens. Bioelectron., 2016, 85, 785—791
[35]	Li Y.F., Wang D., Liao Z., Kang Y., Ding W. H., Zheng X. J., Jin L. P., J. Mater. Chem. C, 2016, 4(19), 4211—4217
[36]	Su F. F., Guo R., Yu Z. H., Li J.,Liang Z. P., Shi K. R., Ma S. L., Sun G. B., Li H. F., Dalton Trans., 2018, 47(15), 5380—5389
[37]	Li J., Xie L. X., Liang Z. P., Guo R., Liu C. Y., Ma S. L., Chem. J. Chinese Universities, 2018, 39(10), 2154—2160
	(李建, 谢林霞, 梁足培, 国荣, 刘晨昱, 马淑兰. 高等学校化学学报, 2018, 39(10), 2154—2160)
[38]	Li J., Su F. F., Guo R.,Liang Z. P., Ma S. L., Chinese J. Inorg. Chem., 2018, 34(10), 1826—1832
	(李建, 苏飞飞, 国荣, 梁足培, 马淑兰. 无机化学学报, 2018, 34(10), 1826—1832)
[39]	Asadpour-Zeynali K., Amini R., Sens. Actuator B-Chem., 2017, 246, 961—968
[40]	Ma S. L., Fan C. H., Du L., Huang G. L.,Yang X. J., Tang W. P., Makita Y., Ooi K., Chem. Mat., 2009, 21(15), 3602—3610
[41]	Ma S. L., Shim Y., Islam S. M., Subrahmanyam K. S.,Wang P. L., Li H., Wang S. C., Yang X. J., Kanatzidis M. G., Chem. Mat., 2014, 26(17), 5004—5011
[42]	Su F.F., Gu Q. Y., Ma S. L., Sun G. B., Yang X. J., Zhao L. D., J. Mater. Chem. C, 2015, 3(27), 7143—7152
[43]	Lei S. D. Cao X. W., Feng M., Li T., Wang J., Shao M. J., Zhou Q., Wang Y. F., Journal of Light Scattering., 2007, 19(3), 290—295
	(雷思东, 曹学伟, 冯敏, 李涛, 王京, 邵铭杰, 周琦, 王玉芳. 光散射学报, 2007, 19(3), 290—295)
[44]	Ali M., Dutta P., Pandey S., J. Phys. Chem. B, 2010, 114(46), 15042—15051
[45]	Bhagi A., Pandey S., Pandey A., Pandey S., J. Phys. Chem. B, 2013, 117(17), 5230—5240
[46]	Ogawa M., Kuroda K., Chem. Rev., 1995, 95(2), 399—438
[47]	Dong J., Solntsev K. M., Tolbert L. M., J. Am. Chem. Soc., 2009, 131(2), 662—670
[48]	Kwon M. S., Gierschner J.,Yoon S. J., Park S. Y., Adv. Mater., 2012, 24(40), 5487—5492
[49]	Li S. D., Lu J., Wei M., Evans D. G.,Duan X., Adv. Funct. Mater., 2010, 20(17), 2848—2856
[50]	Martwiset S., Nijpanich S., Banturngsaksiri A., Sriring M., Pandhumas T., Youngme S., J. Appl. Polym. Sci., 2013, 130(5), 3205—3211
[51]	Jeong H., Lee B. I., Byeon S. H., ACS Appl. Mater. Interfaces, 2016, 8(17), 10946—10953
[52]	Chen L., Wul C.L., Du P., Feng X. W., Wu P., Cai C. M., Talanta, 2017, 164, 100—109

Related Articles 15

[1]	LIU Dahai, ZHANG Xueyan, FENG Yusha, DU Xianlong, XUE Longqi, DU Jianshi, ZHANG Guirong, YANG Qingbiao, LI Yaoxian. Synthesis of Novel Fluorescein-Thiospirolactams Hg²⁺ Fluorescent Probes and Its Application in vivo^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1412.
[2]	LI Jian,XIE Linxia,LIANG Zupei,GUO Rong,LIU Chenyu,MA Shulan. Luminescence Property and Detection Capability Towards Hg²⁺ of LEuH Composites with Mo $S 4 2 -$ and OS^- Anions^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2154.
[3]	DU Shichao,REN Zhiyu,WU Jun,FU Honggang. Ni-Fe LDH/Reduced Graphene Oxide as Catalyst for Oxygen Evolution Reaction [J]. Chem. J. Chinese Universities, 2016, 37(8): 1415.
[4]	ZHANG Tao, TANG Yongjia, XU Liang, LIU Keliang. Synthesis of a New Cyanoacrylate Monomer and Its Application in Fluorescence Imaging in vivo^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1168.
[5]	TIAN Tao, LIU Chang, HE Song, ZENG Xianshun. Molecular Full-adder and Full-subtractor Logic Circuit Based on Fluorescein Derivatives^† [J]. Chem. J. Chinese Universities, 2015, 36(2): 260.
[6]	SUN Mei-Yu, PANG Xiu-Jiang, MA Xiu-Ming, HOU Wan-Guo. Preparation and Particle Size Controllability of Mg-Al Layered Double Hydroxides via Coprecipitation Method Using T-type Microchannel Reactor [J]. Chem. J. Chinese Universities, 2013, 34(7): 1691.
[7]	MA Xiu-Ming, PANG Xiu-Jiang, QUAN Zhen-Lan, HOU Wan-Guo. Synthesis and Characterization of 10-Hydroxyl Camptothecin-Sebacate-LDH Nanohybrid [J]. Chem. J. Chinese Universities, 2013, 34(4): 913.
[8]	FU Hua-Kang, YE Wei-Juan, LIU Meng-Ying, HU Ji, DU Miao, ZHENG Qiang. Preparation of Layered Double Hydroxide/Carbon Nanotubes Composite and its Dispersion in Organic Solvents [J]. Chem. J. Chinese Universities, 2013, 34(3): 538.
[9]	CAO Tian-Chi, CHEN Guang-Ming, GUO Cun-Yue. Poly(ethylene terephthalate)/Layered Double Hydroxide Nanocomposites [J]. Chem. J. Chinese Universities, 2013, 34(10): 2239.
[10]	WANG Heng-Guo, LIU Da-Hai, ZHANG Chao-Qun, LI Yao-Xian, YANG Qing-Biao, DU Jian-Shi. Preparation and Characterization of Fluorescent Nanofiber Based on Fluorescein [J]. Chem. J. Chinese Universities, 2012, 33(05): 1074.
[11]	XU Kong-Li, CHEN Guang-Ming, SHEN Jian-Quan. Synthesis of Organically-modified Layered Double Hydroxides by Direct Decarbonation [J]. Chem. J. Chinese Universities, 2012, 33(04): 649.
[12]	GAN Xiao-Juan, LIU Shao-Pu, LIU Zhong-Fang, HU Xiao-Li. Fluorescence Quenching Method for the Determination of Carbazochromum with Halide Fluorescein Dyes [J]. Chem. J. Chinese Universities, 2012, 33(04): 683.
[13]	LIU Guo-Peng, LIU Shang-Ying, WANG Jun, SUN De-Jun*. Double Flocculation in Aqueous Dispersion of Layered Double Hydroxide Particles Induced by Sodium Polyacylate [J]. Chem. J. Chinese Universities, 2010, 31(10): 2030.
[14]	ZHANG Hui-Zhong, NIE Fei, Lü Jiu-Ru. Post-chemluminescence Reaction of Some Nitrogenous Organic Compounds in the N-Chlorosuccinimide-dichlorofluorescein System [J]. Chem. J. Chinese Universities, 2010, 31(1): 51.
[15]	LIANG Chong-Yang¹, XU Wei-Qing², CAO Yan-Xin², LIU Li-Xia³, ZHANG Shu-Qin¹, LIU Zhi-Yi¹, LI Hong-Rui¹, LI Bai-Zhi¹, SUN Fei^1* . Dynamic Observation of Cellular Localization of Fluorescein Isothiocyanate Labeled Recombinant Ganoderma Lucidum Immunoregulatory Protein(rLz-8) in NB4 APL Cell [J]. Chem. J. Chinese Universities, 2009, 30(3): 489.