Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 507.
• Synthetic Sciences • Previous Articles Next Articles
REN Yan-Ping, LONG La-Sheng
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Abstract:
On the effort to mimick the function of galactose oxidase (GO), only three copper(Ⅰ) complexes reported can catalyze efficiently the aerobic oxidation of primary and second alcohols to the corresponding aldehydes and ketons or 1,2-glycols by oxidative C-C coupling with concomitant formation of H2O2[1-3]. However, those complexes were catalytically inactive, when using copper(Ⅱ) instead of copper(Ⅰ). We report here an example of oxidation of N, N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the corresponding aldehyde (L1O) catalytzed by copper(Ⅱ) ion.
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REN Yan-Ping, LONG La-Sheng. Oxidation of N,N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the Corresponding Aldehyde Catalyzed by Copper(Ⅱ) Ion[J]. Chem. J. Chinese Universities, 2000, 21(S1): 507.
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http://www.cjcu.jlu.edu.cn/EN/Y2000/V21/IS1/507