CJCU

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 133.

• Chemistry in Energy Sciences • Previous Articles     Next Articles

Investigation of Partial Oxidation of Methane to Syngas on Rh/SiO2-Using 1H-NMR

WU Ting-Hua1, YAN Qian-Gu2, CHAO Zi-Sheng2, LUO Chun-Rong2, YE Jian-Liang2, WAN Hui-Lin2   

  1. 1. Department of Chemistry and Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004;
    2. State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry and Institute of Physical Chemistry, Xiamen University, Xiamen 361005
  • Online:2000-12-31 Published:2000-12-31
  • Contact: WAN Hui-Lin
  • Supported by:

    This research was sponsored by the Ministry of Science and Technology of China through Grant G1999022408 and the Ministry of Education through Doctoral Foundation.

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Abstract:

In our previous work, POM has been investigated by the pulse reaction with CH4 and CH4/O2 respectively, on Rh/SiO2 catalyst. Kinetic isotopic effect was also studied by using CD4 and CD4/O2. The results suggest that POM may proceed most possibly via a mechanism of surface carbon species reacting with surface oxygen. In the present work, 1H MAS NMR was utilized to investigate the POM mechanism in aiming of presenting additional evidence.

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