Cycloaddition of Bu3P-CS2 Adduct with the Compounds Bearing Unsaturated Bonds

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (S1): 134.

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Cycloaddition of Bu₃P-CS₂ Adduct with the Compounds Bearing Unsaturated Bonds

LIU Yu-Xiu, XU Cheng-Fu, WANG Wen-Hu, CAO Ru-Zhen, LIU Lun-Zu

National Key Laboratory fo Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Received:2001-07-31 Online:2001-12-31 Published:2001-12-31
Contact: lunzuliu@mail.zlnet.com.cn E-mail:lunzuliu@mail.zlnet.com.cn

Abstract

Abstract:

The one-pot reaction of Bu₃P-CS₂ adduct with the compounds bearing unsaturated bonds (electric rich alkynes, phosphonyl alkynes or alkenes) and aldehyde affords dithioles or dithiolanes in mediocre yields. Bu₃P-CS₂ adduct reacts with azo-compounds and aldehyde to give the thiodiazolidine thiones. The mechanism of reaction is discussed.

Key words: Bu₃P-CS₂ adduct, l,3-dithioles, l,3-dithiolanes, thiodiazolidine thiones, cycloaddition

CLC Number:

O627

TrendMD:

LIU Yu-Xiu, XU Cheng-Fu, WANG Wen-Hu, CAO Ru-Zhen, LIU Lun-Zu. Cycloaddition of Bu₃P-CS₂ Adduct with the Compounds Bearing Unsaturated Bonds[J]. Chem. J. Chinese Universities, 2001, 22(S1): 134.

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Cycloaddition of Bu₃P-CS₂ Adduct with the Compounds Bearing Unsaturated Bonds

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