Chem. J. Chinese Universities ›› 1982, Vol. 3 ›› Issue (S1): 97.
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Han Yande, Li Baifu, Zhu Yukui, Sun Chia-chung
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In this paper, a theoretical analysis of the spectra for the ions Re+4 (5d3) and Os+4(5d4) in K2PtCl6 crystal is performed by means of ligand field method proposed by Tang et al. Also, in the SLГSГtτ scheme of octahedral symmetry, the energy curves in terms of crystal field and spin-orbital parameters are worked out. The results of our analysis are in accord with those obtained via a strong field treatment by Dorain[9-10], but some spectra terms which have been inadequately assigned by Dorain[9-l0] are corrected.
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Han Yande, Li Baifu, Zhu Yukui, Sun Chia-chung. THE ANALYSIS OF THE LIGAND FIELD THEORY OF CRYSTAL SPECTRUM OF d3 (Re+4) AND d4(Os+4) CONFIGURATION[J]. Chem. J. Chinese Universities, 1982, 3(S1): 97.
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