Chem. J. Chinese Universities

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Self-assembly and Photoluminescence of a Unique ZnO Nanostructure

ZHOU Ze-Guang1, CHAI Chun-Fang2, MI Yan1, TAN Xue-Cai1, WU Jian1, HUANG Zai-Yin1,2*, YUAN Ai-Qun1   

    1. School of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, China;
    2. School of Chemistry & Chemical Engineering, Guangxi University, Nanning 530004, China
  • Received:2007-04-03 Revised:1900-01-01 Online:2007-10-10 Published:2007-10-10
  • Contact: HUANG Zai-Yin

Abstract: A unique ZnO nanostructures were synthesized with hydrothermal method. The composition, morphology and size of the sample was determined with XRD, EDX and FE-SEM. Photoluminescence(PL) properties were studied by room-temperature PL spectra, temperature-dependent shifts and its Gaussian-fitted spectra. The results of XRD, EDX and FE-SEM analysis show that the products are the hexagonal wurtzite ZnO nanostructures, with a length of ~10 μm and diameter of ~2 μm; UV, violet and green peaks, which exhibit blue-, S-shaped (red-blue-red) and redshift, respectively, and the decrease of intensity, with the temperature increasing from 8 K to 300 K, are observed in the PL spectra. The original and different temperature dependence of the UV, violet and green peaks is discussed.

Key words: Hydrothermal method, ZnO, Nanostructure, Temperature-dependence PL spectrum

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