Synthesis and Structure of an Inorganic-organic Hybrid Zinc Phosphite†

doi:10.7503/cjcu20131279

Abstract

Abstract:

A 3D inorganic-organic hybrid zinc phosphite (C₆N₂H₁₆)_0.5ZnHPO₃(ZnHPO-CJ15) has been hydrothermally synthesized. Crystal data for ZnHPO-CJ15 are as follows: monoclinic system, P2₁/c space group, a=1.19587 nm, b=0.82766(5) nm, c=0.77756(5) nm, α=90.00°, β=95.8370(10)°, γ=90.00°, V=0.76562(8) nm³ and Z=1. Single-crystal structure analysis reveals that the inorganic framework of ZnHPO-CJ15 is constructed by the connection of HPO₃ pseudo-pyramids and ZnO₃N tetrahedral to form 2D layers with 4- and 8-rings. The 1,6-hexanediamine molecules act as the pillars to link the adjacent zinc phosphite layers via N—Zn bonds to form 3D framework.

Key words: Zinc phosphite, Inorganic-organic hybrid compound, Hydrothermal synthesis

CLC Number:

O611.4

TrendMD:

WANG Xuelei, YAN Yan, WU Junbiao, ZOU Yongcun, ZHANG Chuanqi, LI Jiyang. Synthesis and Structure of an Inorganic-organic Hybrid Zinc Phosphite^†[J]. Chem. J. Chinese Universities, 2014, 35(6): 1142.

Figures/Tables 5

References 32

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Compound	ZnHPO-CJ15	V/nm³	0.76562(8)
CCDC No.	974691	Z	4
Crystal size	0.25 mm×0.15 mm×0.10 mm	Calculated density/(Mg·m^-3)	1.765
Empirical formula	(C₆N₂H₁₆)_0.5ZnHPO₃	Completeness to θ=28.31°	99.5%
Formula weight	203.45	Absorption coefficient/mm^-1	3.358
Wavelength/nm	0.071073	Limiting indices	-15≤h≤14, -7≤k≤11, -10≤l≤10
Temperature/K	296(2)	Reflections collected/unique	5508/1910[R_(int) = 0.0199]
Crystal system	Monoclinic	F(000)	412
Space group	P2₁/c	θ range for data collection	3.00° to 28.37°
a/nm	1.19587(7)	Refinement method	Full-matrix least-squares on F²
b/nm	0.82766(5)	Goodness-of-fit on F²	1.039
c/nm	0.77756(5)	Final R indices[I>2σ(I)]	R₁=0.0199, wR₂=0.0531
α/(°)	90.00	R indices(all data)	R₁=0.0222, wR₂=0.0540
β/(°)	95.8370(10)	Largest diff. peak and hole/(e·nm³)	403 and -307
γ/(°)	90.00

Compound	ZnHPO-CJ15	V/nm³	0.76562(8)
CCDC No.	974691	Z	4
Crystal size	0.25 mm×0.15 mm×0.10 mm	Calculated density/(Mg·m^-3)	1.765
Empirical formula	(C₆N₂H₁₆)_0.5ZnHPO₃	Completeness to θ=28.31°	99.5%
Formula weight	203.45	Absorption coefficient/mm^-1	3.358
Wavelength/nm	0.071073	Limiting indices	-15≤h≤14, -7≤k≤11, -10≤l≤10
Temperature/K	296(2)	Reflections collected/unique	5508/1910[R_(int) = 0.0199]
Crystal system	Monoclinic	F(000)	412
Space group	P2₁/c	θ range for data collection	3.00° to 28.37°
a/nm	1.19587(7)	Refinement method	Full-matrix least-squares on F²
b/nm	0.82766(5)	Goodness-of-fit on F²	1.039
c/nm	0.77756(5)	Final R indices[I>2σ(I)]	R₁=0.0199, wR₂=0.0531
α/(°)	90.00	R indices(all data)	R₁=0.0222, wR₂=0.0540
β/(°)	95.8370(10)	Largest diff. peak and hole/(e·nm³)	403 and -307
γ/(°)	90.00