Chem. J. Chinese Universities ›› 2012, Vol. 33 ›› Issue (09): 1895.doi: 10.3969/j.issn.0251-0790.2012.09.004

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Preparation of Self-assembled Titanate Aggregates with Regular Structure

PAN Yan1,2, GUO Yu-Peng1, SONG Wen-Bo1, LIU Zhi-Hui3   

  1. 1. College of Chemistry, Jilin University, Changchun 130012;
    2. College of Chemistry, Changchun Normal University, Changchun 130032;
    3. Stomatology Hospital, Jilin University, Changchun 130021, China
  • Received:2012-02-07 Online:2012-09-10 Published:2012-08-14
  • Contact: Zhihui Liu E-mail:liuzhihui1975@sina.com

Abstract:

Bird's nest-like self-assembly titanate nanoribbon aggregates, fluff sphere-like self-assembly titanate nanoribbon aggregates and urchin-like self-assembly titanate nanotube aggregates were prepared without template from Ti flake(or TiO2 powder, P25) under hydrothermal conditions by adjusting NaOH concentration and cooling temperature. Cattail-like self-assembly titanate-sodium carbonate self-assembly complex aggregates were prepared with sodium carbonat as template. A possible two-stage growth mechanism involving the initial formation of primary 1D nanostructures that subsequently self-assemble was proposed. This method will provide a promising approach that the function materials are assembled into highly ordered structure in the ideal way and lend itself to the research on microdevice.

Key words: Titanate, Hydrothermal preparation, Self-assembled aggregate

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