Electrospinning Preparation and Properties of Eu(BA)3phen/PANI/PVP Luminescence-electricity Bifunctional Composite Nanofibers

doi:10.3969/j.issn.0251-0790.2012.08.005

Abstract

Abstract: Luminescence-electricity bifunctional Eu(BA)₃phen/PANI/PVP composite nanofibers were prepared through the doping of polyaniline(PANI) and rare earth complex in polyrinyl phrrolidone(PVP) via electrospinning. Scanning electron microscope(SEM), energy dispersive spectrometer(EDS), fluorescence spectrometer and broadband dielectric spectrometer were used to characterize the samples. The results indicated that the average diameter of the Eu(BA)₃phen/PANI/PVP composite nanofibers was (270±31) nm. Under excitation of 275 nm, the Eu(BA)₃phen/PANI/PVP composite nanofibers emitted the predominant emission at 580, 594 and 617 nm, corresponding to ⁵D₀→⁷F₀, ⁵D₀→⁷F₁ and ⁵D₀→⁷F₂ transitions of Eu³⁺, respectively. The strongest emission intensity occurred when the mass ratios of Eu(BA)₃phen: PANI: PVP was 15: 10: 100, the electric conductivity of the composite nanofibers increased with the increase of PANI content, and reached 1.5×10^-6 S/cm in high frequency electric field(10⁶ Hz) when the mass ratio of PANI to PVP was 50%.

Key words: Electrospinning, Eu(BA)₃phen/PANI/PVP, Nanofiber, Polyaniline

CLC Number:

O614.32
TB34

TrendMD:

WANG Ying-He, WANG Jin-Xian, DONG Xiang-Ting, YU Wen-Sheng, LIU Gui-Xia. Electrospinning Preparation and Properties of Eu(BA)₃phen/PANI/PVP Luminescence-electricity Bifunctional Composite Nanofibers[J]. Chem. J. Chinese Universities, 2012, 33(08): 1657.

References

[1] DONG Xiang-Ting(董相廷), LIU Li(刘莉), WANG Jin-Xian(王进贤), LIU Gui-Xia(刘桂霞). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(1): 20-25 [2] LI Yue-Jun(李跃军), CAO Tie-Ping(曹铁平), WANG Chang-Hua(王长华), SHAO Chang-Lu(邵长路). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(11): 2490-2497 [3] Zhang H., Song H. W., Yu H. Q., Bai X., Li S. W., Pan G. H., Dai Q. L., Wang T., Li W. L., Lu S. Z., Ren X. G., Zhao H. F.. J. Phys. Chem. C[J], 2007, 111(17): 6524-6527 [4] LI Yue-Jun(李跃军), CAO Tie-Ping(曹铁平), SUN Xin-Li(孙新丽), SHAO Chang-Lu(邵长路). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(1): 16-19 [5] SUN Xia(孙霞), DONG Xiang-Ting(董相廷), WANG Jin-Xian(王进贤), LIU Gui-Xia(刘桂霞). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(10): 2262-2267 [6] LI Xiang(李响), ZHAO Yi-Yang(赵一阳), LU Xiao-Feng(卢晓峰), WANG Hai-Ying(王海鹰), WANG Ce(王策). Chem. J. Chinese Universities(高等学校化学学报)[J], 2006, 27(10): 2002-2004 [7] HUANG Hui-Min(黄绘敏), LI Zhen-Yu(李振宇), YANG Fan(杨帆), WANG Wei(王威), WANG Ce(王策). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(6): 1200-1202 [8] SONG Chao(宋超), DONG Xiang-Ting(董相廷), WANG Jin-Xian(王进贤), LIU Gui-Xia(刘桂霞). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(8): 1673-1679 [9] Feng C. H., Ruan S. P., Zhu L. H., Li C., Li W., Chen W. Y., Chen L. H., Zhang X. D.. Chem. Res. Chinese Universities[J], 2011, 27(5): 720-723 [10] Lu J., Liu J. G., Song X. F., Chen X. S., Wu X. D.. Chem. Res. Chinese Universities[J], 2011, 27(3): 524-527 [11] Sambaer W., Zatloukal M., Kimmer D.. Chem. Eng. Sci.[J], 2011, 66(4): 613-623 [12] Corres J. M., Garcia Y. R., Arregui F. J., Matias IR.. Sens. J. IEEE[J], 2011, 11(10): 2383-2387 [13] Sell S. A, Wolfe P. S., Ericksen J. J., Simpson D. G., Bowlin G. L.. Tissue Eng. Part A[J], 2011, 17(21/22): 2723-2737 [14] Chen S. L., Hou H. Q., Harnisch F., Patil S. A., Carmona-Martinez A. A., Agarwal S., Zhang Y. Y., Sinha-Ray S., Yarin A. L., Greiner A., Schrder U.. Energ. Environ. Sci.[J], 2011, 4: 1417-1421 [15] Zhang H., Song H. W., Ding Y., Wang L., Pan G. H., Bai X., Fan L., Lu S. Z., Zhao H. F., Wang F.. J. Phys. Chem. C[J], 2008, 112: 9155-9162 [16] Liao F. H., Li J. R.. Colloids Surf. A[J], 2011, 10: 1102-1107 [17] Huang L. B., Cheng L. H., Yu H. Q., Zhou L., Sun J. S., Zhong H. Y., Li X. P., Zhang J. S., Tian Y., Zheng Y. F., Yu T. T., Wang J., Chen B. J.. Physica B: Condensed Matter[J], 2011, 406(14): 2745-2749 [18] Wang H. H., He P., Yan H. G., Gong M. L.. Sensors and Actuators B: Chemical[J], 2011, 156(1): 6-11 [19] Yuan J. L., Wang G. L.. J. Fluoresc.[J], 2005, 15(4): 559-568 [20] WANG Hong-Zhi(王宏智), LIU Wei-Hong(刘炜洪), YAO Su-Wei(姚素薇), ZHANG Wei-Guo(张卫国). Chem. J. Chinese Universities(高等学校化学学报)[J], 2012, 33(2): 421-425 [21] Wang H. Z., Zhang P., Zhang W. G.,Yao S. W.. Chem. Res. Chinese Universities[J], 2012, 28(1): 133-136 [22] Bhadra S., Singha N. K., Khastgir D.. Polym. Eng. Sci.[J], 2008, 48: 995-1006 [23] Sinha S., Bhadra S., Khastgir D.. J. Appl. Polym. Sci.[J], 2009, 112: 3135-3140 [24] Sapurina I., Stejskal J.. Polym. Int.[J], 2008, 57: 1295-1325 [25] Bhadra S., Khastgir D.. Polym. Degrad. Stab.[J], 2008, 93: 1094-1099 [26] Bhadra S., Khastgir D.. Polym. Degrad. Stab.[J], 2007, 92: 1824-1832 [27] ZHANG Qing-Hua(张清华), WANG Xian-Hong(王献红), JING Xia-Bin(景遐斌). Chemistry World(化学世界)[J], 2001, 5: 242-244 [28] Kim J., Kwon S., Ihm D. W.. Current Applied Physics[J], 2007, 7: 205-210 [29] WANG Zheng-Xiang(王正祥), CHEN Hong(陈洪), TAN Mei-Jun(谭美军). Spectroscopy and Spectral Analysis(光谱学与光谱分析)[J], 2005, 25(7): 1106-1109

Electrospinning Preparation and Properties of Eu(BA)₃phen/PANI/PVP Luminescence-electricity Bifunctional Composite Nanofibers

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WU Yu, LI Xuan, YANG Hengpan, HE Chuanxin. Construction of Cobalt Single Atoms via Double-confinement Strategy for High-performance Electrocatalytic Reduction of Carbon Dioxide [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220343.
[2]	XIE Fan, CHEN Shanshan, ZHUO Longhai, LU Zhaoqing, GAO Kun, DAI Qiyang. Fabrication of Poly（p-xylene） Nanofiber Arrays by CVD Liquid Crystal Template Method and Their Degradability [J]. Chem. J. Chinese Universities, 2021, 42(8): 2643.
[3]	YANG Sixian, ZHONG Wenyu, LI Chaoxian, SU Qiuyao, XU Bingjia, HE Guping, SUN Fengqiang. Photochemical Fabrication and Performance of Polyaniline Nanowire/SnO₂ Composite Photocatalyst [J]. Chem. J. Chinese Universities, 2021, 42(6): 1942.
[4]	LI Min, ZHAO Chun, FENG Qinzhong, FENG Jian, MENG Xiaojing. Experimental and DFT Studies on the Adsorption of Cd（II） Ions from Aqueous Solutions by Nanofiber Modified Thiourea Groups [J]. Chem. J. Chinese Universities, 2021, 42(12): 3680.
[5]	QIN Chunping, WANG Xianliu, TANG Han, YI Bingcheng, LIU Chang, ZHANG Yanzhong. Osteogenesis-promoting Effects of the Electrospun Nanofibers Containing Decellularized Bone Matrix ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 780.
[6]	KONG Jinfeng, ZHU Yuzhang, JIN Jian. Sulfonated Cellulose Nanofibers Film Supported Nanofiltration Membrane for High-flux and High-rejection Desalination ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 690.
[7]	REN Wen, ZHANG Guoli, YAN Han, HU Xinghua, LI Kun, WANG Jingfeng, LI Ruiqi. Preparation of Superhydrophobic Polyaniline/Polytetrafluoroethylenethylene Composite Membrane and Its Separation Ability for Oil-Water Emulsion ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 846.
[8]	JI Tianyi, LIU Xiaoxu, ZHAO Jiupeng, LI Yao. Synthesis and Lithium-storage Characteristics of Three-dimensional Cross-linked Graphene Nanofibers ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 821.
[9]	WANG Xia, LIU Yanji, JIA Yongfeng, JI Lei, HU Quanli, DUAN Limei, LIU Jinghai. Preparative Chemistry of N-containing Porous Carbon Nanofibers for Capacity Improvement in Lithium-sulfur Battery ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 829.
[10]	HAN Zhiying,LI Youji,CHEN Feitai,TANG Senpei,WANG Peng. Preparation of ZnO/Ag₂O Nanofibers by Coaxial Electrospinning and Study of Their Photocatalytic Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 308.
[11]	LING Xuxia, LONG Zhu, WANG Shihua, LI Zhiqiang, GUO Shuai, ZHANG Dan. Surface Modified Aramid Pulp with Polyaniline and Conductivity of Its Paper-based Materials [J]. Chem. J. Chinese Universities, 2020, 41(11): 2553.
[12]	WANG Yihan,YIN Qiang,DU Kai,YIN Qinjian. Polypyrrole/Polyaniline Nanocomposite Nanotubes with Enhanced Thermoelectric Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 175.
[13]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[14]	WANG Yongpeng,XU Zibo,LIU Mengzhu,ZHANG Haibo,JIANG Zhenhua. Non-enzymatic Glucose Sensor Based on the Electrospun Porous Foamy Copper Oxides Micro-nanofibers^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1310.
[15]	CAI Jiao,YU Qiongwei,HE Xiaomei,XU Jing,DING Qiong,FENG Yuqi. Preparation of SiW₁₁ Incorporated SiO₂ Nanofibers(SiW₁₁/SiO₂) and Its Application in the Analysis of Polyamines in Arabidopsis^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 901.