Chem. J. Chinese Universities ›› 1981, Vol. 2 ›› Issue (1): 105.
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Wu Tonghao, Yang Hongmao, Zhao Fangqing
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Abstract: Infrared spectra of ethylene chemisorbed on silicasupported palladium at 15℃ have been obtained.On hydrogenation of the chemisorbed surface species at 15℃, ethane and a smaller amount of n-butane were formed.The experiment indicated that ethylene chemisorbed on silicasupported palladium formed three surface species: the σ-bond type surface species PdCH2CH2Pd; the n-butyl type surface species CH3 CH2 CH2 CH2 Pd, probably via a self-hydrogenation and surface dimerization; and the surface carbide probably via the dissociative chemisorption of ethylene.
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Wu Tonghao, Yang Hongmao, Zhao Fangqing. INFRARED STUDY OF ETHYLENE CHEMISORBED ON SILICASUPPORTED PALLADIUM[J]. Chem. J. Chinese Universities, 1981, 2(1): 105.
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