Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (5): 436.

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Ligand Field Analysis of the Electronic Spectra of Tetragonal Distrorted Cobalt (Ⅱ) Complex

Liao Daizheng, Zhang Zhiyong, Wang Genglin   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1984-10-11 Online:1986-05-24 Published:1986-05-24

Abstract: Electronic spectra of 14-membered hexaaza macrocyclic Co ( Ⅱ ) complex, [CoL(SCN)2]·5H2O, have been treated by the ligand field theory. Values of the various ligand field parameters have been obtained and their chemical significance was discussed. The transition energies have been derived form the parameters and d7 energy matrices.Fairly good agreement has been obtained between the calculated and experimental values.

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