Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (10): 877.
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Zhang Lun, Ding Zirong, Zhang Guomin
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Abstract: The pyridine oxide(PYO)complexes of rare earth(Ⅲ)decahydrodecabo-rates were prepared by the reactions between Ln2(B10H10)3nH2Oand PYOin ethanol medium.These complexes were characterized by elemental analysis,electro-conductance,IR,Raman,UVspectra,and TG-DTA They have the follow ing formulae [Ln(PYO)7]2(B10H10)3(Ln=Nd,Sm,Eu,Gd,Ho,Er,Tm,Yb).The PYOis boned to the rare earth via the oxygen atom.The molar conductance data indicate that these complexes are ionic and behave as 2:3 electro-tyles in water.These complexes are thermally stable and their thermal behavior were approached.
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Zhang Lun, Ding Zirong, Zhang Guomin . Studies on Rare Earth Hydroboron Compounds (Ⅳ)—The Pyridine Oxide Complexes of Rare Earth(Ⅲ) Decahydrodecaborates[J]. Chem. J. Chinese Universities, 1986, 7(10): 877.
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http://www.cjcu.jlu.edu.cn/EN/Y1986/V7/I10/877
