Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (11): 1025.
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AVu Tonghao, Yang Hongmao, Wang Guojia
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Abstract: The chemisorption and catalytic conversion of tcrt-butanol have been investigated by means of FTIR. At 15℃, chemisorption of tert-butanol has been found to occur on the catalyst surface, the probable chemisorbed state being (CH3)3C, π-allyl-like species CH2=C(CH3)=CH2 and σ-allyl species CH2C(CH3)=CH2. At 50℃, this π-allyl-like species desorbed to give gaseous isobutene.
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AVu Tonghao, Yang Hongmao, Wang Guojia . Infrared Study of Chemisorption and Conversion of Tert-Butanol on H5PMo10V2O40/SiO2 Catalyst[J]. Chem. J. Chinese Universities, 1985, 6(11): 1025.
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