Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (2): 146.

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Carbon13 Chemical Shifts in Transition Metal Complexes

You Xiaozeng1, R. F. Fenske2, D. G. Freier2   

  1. 1. Nanjing University, Nanjing;
    2. University of Wisconsin, U.S.A.
  • Received:1983-06-02 Online:1985-02-24 Published:1985-02-24

Abstract: The results for the first overlaping sphere Xa-SWchemical shift calculation are shown to reproduce the trends in13C NMRexperiments for the CO, C9, CNand C5H5 ligands in transition metal complexes Ni(CO)4, Cr(CO)5CSand Fe(CBH5)(CO)2CN.The relationship between the chemical shifts with the electronic structure and bonding have been discussed.

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