Synthesis, Characterization and Electrochemistry Properties of Novel Tailed 5-(4-Nicotinicoxylhexyloxy)phenyl-10,15,20-triphenylporphyrin and Its Complexes

Chem. J. Chinese Universities

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Synthesis, Characterization and Electrochemistry Properties of Novel Tailed 5-(4-Nicotinicoxylhexyloxy)phenyl-10,15,20-triphenylporphyrin and Its Complexes

SU Lian-Jiang¹, LI Wei-Hong¹, XU Chun-Fang¹, WANG Li-Min¹, CHENG Xiu-Li², SHI Tong-Shun^2*

1. Department of Chemistry, Daqing Normal College, Daqing 163712, China;
2. College of Chemistry, Jilin University, Changchun 130021, China

Received:2008-01-04 Revised:1900-01-01 Online:2008-09-10 Published:2008-09-10
Contact: SHI Tong-Shun

Abstract

Abstract: A novel tailed 5-(4-nicotinicoxylhexyloxy)phenyl-10,15,20-triphenylporphyrin(H₂NHPTPP) and its Mn, Fe, Co, Ni, Cu and Zn complexes were synthesized and characterized by means of elemental analysis, UV-Vis, IR, MS and ¹H HMR spectroscopies. The electrochemical properties were studied via cyclic voltammetry. The results show that there are great differences in the infrared spectra, UV-Vis spectra, mass spectra and ¹H NMR spectra between the ligand and the complexes. The cyclic voltammetry of NHPTPPMnCl and NHPTPPFeCl are different from the ligand and NHPTPPNi, NHPTPPCu and NHPTPPZn, which showed not only the redox of the porphyrin ring, but also the redox of the metal ion.

Key words: Nicotinic acid, Tailed porphyrin, Synthesis, Cyclic voltammetry

CLC Number:

O614
O657.1

TrendMD:

SU Lian-Jiang¹, LI Wei-Hong¹, XU Chun-Fang¹, WANG Li-Min¹, CHENG Xiu-Li², SHI Tong-Shun^2*. Synthesis, Characterization and Electrochemistry Properties of Novel Tailed 5-(4-Nicotinicoxylhexyloxy)phenyl-10,15,20-triphenylporphyrin and Its Complexes[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Characterization and Electrochemistry Properties of Novel Tailed 5-(4-Nicotinicoxylhexyloxy)phenyl-10,15,20-triphenylporphyrin and Its Complexes

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