CJCU

Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (10): 937.

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Crystal and Molecular Structures of a Cluster Compound (Mo2FeS8O)[(C4H9)4N]3HOCH2CH3OH

Yang Guangdi1, Zhang Zhigui2   

  1. 1. Institute of Theoretical Chemistry of Jilin University, Changchun;
    2. Chemistry Department of Jilin University, Changchun
  • Received:1986-05-23 Online:1987-10-24 Published:1987-10-24

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Abstract: The title compound was synthesized by reacting certain amount of (NH4)2-MoS4with FeCl3in HOCH2CH2OH-NaOCH2CH2ONa solution. The cluster compound crystallizes in the monoclinic space group p21/c with α=16.889(6)Å, b=16.617(8)Å, c=24.527(9)Å, β=99.66(3)°, V=6785.62Å3, Z=4. The structure was solved by combining pattcrson function analysis and fourier iteration technique, and refined by using blocked-least-squares program up to the final R=0.066 Rw=0.06.Comparison with related structure shows that the presence of HOCH2CH2OH in the crystals changes its structural symmetry remarkably.

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