Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (8): 686.
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Cao Xizhang, Zheng Guodong
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Abstract: In this work, optically transparent thin-layer electrode (OTTLE) was used to detect the intermediate of electrocatalytic reduction of CO2The results showed that in the presence of imidazole (Im),the intermediate CO2·Co(Ⅰ) TMAPI·lm, was detected by UV/Vis absorption pectrum at -1.0V (SCE). The characteristic peaks were 434.0nm, 555.4nm and 603.6nm. We can come to the concolusion that CO2was activated by the formation of the intermediate CO2-Co(Ⅰ)-TMAPI.
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Cao Xizhang, Zheng Guodong . Detection of the Intermediate of the Electrocatalytic Reduction of Carbon Dioxide Using Optically Transparent Thin-Laver Electrode[J]. Chem. J. Chinese Universities, 1987, 8(8): 686.
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http://www.cjcu.jlu.edu.cn/EN/Y1987/V8/I8/686