Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (1): 67.
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Wang-Zheng, Wu Jian. Qiao-Yinan, Wang Youwen, Shen Zhiquan
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Abstract: The high cis-polyacetylene filmis with metallic appearance were synthesized by new coordination catalysts composed of Fe(naph), or Fe(P204)3 or Fe(P507)3 and aluminum trialkyl at room temperature.The resultant polyacetylene was charac-terized by IR, ESR, X-ray diffraction, SEM, TEM, electrical resistivity measurement and elemental analysis. The higher activity of polymerization and direct forming films of polyacetylene having rich cis-content were obtained with these catalysts.The single crystal and spot diagram from electron diffraction of polyaCetyl-ene prepared with the Fe(P507)3 system were found. Electrochemistry and batteryof polyacetylene were studied too.
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Wang-Zheng, Wu Jian. Qiao-Yinan, Wang Youwen, Shen Zhiquan . Synthesis of Cis-Polyacetylene with New Catalysts Consisting of Ferric Phosphates and Naphthenate[J]. Chem. J. Chinese Universities, 1988, 9(1): 67.
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http://www.cjcu.jlu.edu.cn/EN/Y1988/V9/I1/67