Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (2): 168.

• Articles • Previous Articles     Next Articles

The Application of FT-IR-EMS Method in the Study of the Dynamics of PEP/PU IPN Formation

Ma Song, Tang Daxin, Li Yuwei, Zhang Jun, Zhang Donghua, Tang Xinyi   

  1. Chemistry Department, Jilin University, Changchun
  • Received:1986-05-06 Online:1988-02-24 Published:1988-02-24

Abstract: The FT-IR emission spectra(FT-IR EMS) of IPN during polymerizationunder 140℃ are measured using modified 5DX FT-IR spectrometer. The reactionextents and kinetic constants are calculated by peak-area ratio method. "The results show that both the polymerization of EPOand the formation of PUare firstorder reaction and kepo=0.035, kepo in IPN= 0.10, and kPU=0.15. The relation between reaction and structure is discussed. The results show that FT-IR EMSis an effective technique in the study of polymer reaction kinetic.

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