Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (11): 1146.

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The Measuring About Kinetic Parameters of Curing Reaction for HTPB-TDI by Thermokinetics

Yan Hua, Zhou Xuzliang, Li Mingxia   

  1. Department 5, National University of Defence and Technology, Changsha
  • Received:1987-06-10 Online:1988-11-24 Published:1988-11-24

Abstract: The kinetics of polymerization was studied by thermokinectics, based on the conduction type automatic calorimeter (Model RD-I) , we devised the reactor. The kinetic parameters of curing reaction (apparent activation energies, the rate constant of reaction) were studied for the system hydroxy-terminated poly-butadiene (HTPB) and tolyene diisocynate (TDI), the results are in agreement with the values which were determited by TBA,infrared spectrograph and the visco-metric method.

Key words: Thermokinetics, Kinectics of Polymerization, Hydroxy -terminated Polybutadience(HTPB)

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