Chem. J. Chinese Universities

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Synthesis, Crystal Structure and Properties of an Inorganic/Organic Hybrid Supramolecule Compound of the Four-electron Reduced α-Keggin-type Phosphomolybdate

ZHANG Li-Juan2, LI Yu-Hao2, ZHOU Yun-Shan1,2*, HAN Rui-Xue2, ZHANG Li-Hui2   

    1. State Key Laboratory of Chemical Resource Engineering,
    2. College of Science, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2008-03-07 Revised:1900-01-01 Online:2008-08-10 Published:2008-08-10
  • Contact: ZHOU Yun-Shan

Abstract: The first four-electron reduced α-Keggin type phosphomolybdate-based organic-inorganic hybrid supramolecule compound was hydrothermally synthesized in the necessary presence of copper ion by reacting α-Keggin type phosphomolybdic acid and 1,6-hexanediamine, and characterized thoroughly via single-crystal X-ray diffraction, elemental analysis, IR,UV-Vis, TG/DTA, XPS, magnetic and electrochemical studies.

Key words: Heteropoly blue, Supramolecule, Four-electron reduced

CLC Number: 

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