Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (12): 1381.

• Articles • Previous Articles     Next Articles

An ESR Study of the Organozirconium (Ⅲ) Complexes

Wang Ji-tao, Bai Ling-jun, Zhang Yun-wen, Li Jiang-sheng   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1990-04-14 Online:1990-12-24 Published:1990-12-24

Abstract: Thermo-stable paramagnetic organozirconium (Ⅲ) complexes are formed when thermolysis or photolysis of Cp2ZrHCl,(Cp2ZrCl)2 or Cp2ZrH(μ-H)(Cp=η5-C5H5) are carried out in the presence of nitrogen or phosphorus ligands. ESRspectra of these complexes are monitored and ESR parameters of 17 complexes are given.

Key words: Zirconium hydrogen agent, Organozirconium (Ⅲ) complex, ESR spectra

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