Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (5): 653.

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Angular Overlap Model Calculation and Its Simplification

Zhao Ming, Sun Sui   

  1. Department of Chemistry, Hunan Normal University, Cliangsha, 410006
  • Received:1989-10-05 Online:1991-05-24 Published:1991-05-24

Abstract: The formulation is developed by which the values of Group Overlap Integrals(GOIs) between orbitals of the central atom and ligands'orbitals in a coordination compound can be carried out. GOIs whose orbitals are transformed under molecular point groups are rewritten as those only under rotational point groups on condition that there exists a simple relation between the two types of GOIS. The calculations using Angular Overlap Model on GOIs are simplified.

Key words: Group Overlap Integrals, Molecular and rotational point groups, Angular overlap model

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