Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1469.

• Articles • Previous Articles     Next Articles

Synthesis and Characterization of Poly(p-Phenylphenoxyphosphazine)

ZHENG Fu-An, LIN Zhi-Hong, YIE Chun-Min, TANG Xin-Yi   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1991-11-11 Revised:1992-03-16 Online:1992-11-24 Published:1992-11-24

Abstract: The solution polymerization method of poly(dichlorophosphazene)from hexachlorocy-clotriphosphazene with a-chloronaphthalene as solvent was investigated and the title polymer was prepared from polydichlorophosphazene and sodium p-pheny|phenolate.At the same time,the IR,1H NMR of the title polymer were determined.The Mn of this polymer estimated by GPC is 6×104 and the glass transition and viscous flow temperatures determinated by TBAare 0℃ and 130℃ respectively.

Key words: Hexachlorocyclotriphosphazene, Poly (dichlorophosphazene), α-Chloronaphthalene, p-Phenylphenol

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