Spectral Detection for Vitamin C and H2O2 Based on the Reversible Color Change and Luminescent Switching Properties of P2Mo18O626-@Tb3+ Mixed Solution†

doi:10.7503/cjcu20180743

Abstract

Abstract:

Based on the functional complementarity and energy transfer between the reversible discoloration polyoxoanions P₂Mo₁₈ $O 62 6 -$ and green luminescent Tb³⁺ ions, the color of the P₂Mo₁₈ $O 62 6 -$ @Tb³⁺mixed solution changed from light yellow to dark blue and as meanwhile the luminescence quenched under the reduction of VC. On the contrary, the dark blue color faded and the luminescence recovered correspondingly under the oxidation of H₂O₂. And the P₂Mo₁₈ $O 62 6 -$ @Tb³⁺ mixed solution exhibited a reversible chemical response discoloration and luminescent switching properties. The VC concentrations were quantitatively measured by UV-Vis and PL spectroscopy, and the corresponding linear equations were acquired by drawing VC concentrations with UV-Vis absorbance at 800 nm and fluorescence intensity at 547 nm. And the detection limits were 3.40×10^-3 and 0.21 μmol/L, respectively. The response rates of VC and H₂O₂ detection were investigated by UV-Vis and fluorescence kinetic methods, and the response time were 52 and 320 s, respectively. Finally, the selectivity and reusability of VC detection were studied by UV-Vis spectroscopy and kinetic methods.

Key words: Polyoxometalates, Vitamin C, Stimuli-response, Fluorescence switch, Biochemical sensor

CLC Number:

O657
O611.3

TrendMD:

WANG Bin,WANG Xiaohong,DUAN Limei,XU Liang,ZHAO Peng,JIAN Jinpeng,LIU Zongrui. Spectral Detection for Vitamin C and H₂O₂ Based on the Reversible Color Change and Luminescent Switching Properties of P₂Mo₁₈ $O 62 6 -$ @Tb³⁺ Mixed Solution^†[J]. Chem. J. Chinese Universities, 2019, 40(4): 676.

Figures/Tables 10

Fig.1 CVs of P2Mo18 solution with different scan rates and VC solution(A), and the relationship of the square of scan rates vs. the oxidation and reduction peak currents(B)

Fig.2 UV-Vis spectra of P2Mo18 solution(A) and fluorescence spectra of the P2Mo18O626-@Tb3+ mixed solution(B)

Fig.3 UV-Vis spectra of 0.1 mol/L VC solution with different concentrations of P2Mo18(A) and P2Mo18@VC mixed solution at different reduction states(B), and the fluorescence spectra of 2 mmol/L P2Mo18 solution with different concentrations of Tb3+(C)(B) a. 0.1 mmol/L P2Mo18+0.1 mol/L VC; b. 2.0 mmol/L P2Mo18+0.1 mmol/L VC. (A) Inset of (A): the absorbance at 650 nm as a function of P2Mo18 concentration. Inset of (C): the fluorescence intensity at 547 nm as a function of Tb3+ concentration.

Fig.4 UV-Vis(A) and fluorescence(B) spectra of P2Mo18O626-@Tb3+ solution under the modulation of VC(a) and H2O2(b)

Fig.5 UV-Vis spectra of P2Mo18O62(6+n)-(a), P2Mo18O626-(c), fluorescence spectra of Tb3+(b)(A) and mechanism diagram of P2Mo18O626-@Tb3+ discoloration and luminescent switching process(B)

Fig.6 UV-Vis spectra(A) and fluorescence spectra(C) of P2Mo18O626-@Tb3+ mixed solution with different concentrations of VC, and the absorbance at 800 nm(B) and the logarithm of the fluorescence intensity at 547 nm(D) as a function of VC concentration

Fig.7 Absorbance at 800 nm of P2Mo18O626-@Tb3+ mixed solution with VC(A) and H2O2(B) vs. time and the absorbance in response equilibrium as a function of VC(C) and H2O2(D) concentrations

Fig.8 Fluorescence intensity at 547 nm of P2Mo18O626-@Tb3+ mixed solution with different concentrations of VC(A) and H2O2(B) vs. time, and the logarithm of fluorescence intensity in response equilibrium as a function of VC(C) and H2O2(D) concentrations

Fig.9 Absorbance at 800 nm of P2Mo18O626-@Tb3+ mixed solution vs. the number of VC and H2O2 cycles

Fig.10 UV-Vis spectra(A) and fluorescence spectra(C) of P2Mo18O626-@Tb3+ mixed solution under different reducing agents, and the corresponding histograms of the absorbance at 800 nm(B) and fluorescence intensity at 547 nm(D) vs. different reducing agentsa. VC; b. oxalic acid; c. glycine; d. alanine; e. glucose; f. maltose.

References 26

[1]	Bohndiek S. B., Kettunen M. I., Hu D., Kennedy B. W., Boren J., Gallagher F. A., Brindle K. M., J. Am. Chem.Soc.,2011, 133(30), 11795—11801
[2]	Guo Q. H., Wu T. T., Liu L. J., Hou H. Q., Chen S. L., Wang L., J. Mater. Chem.B,2018, 6(28), 4610—4617
[3]	Zheng S. T., Yang G. Y., Chem. Soc.Rev.,2012, 41(22), 7623—7646
[4]	Yan L. L., Liu C. G., Jiang M. X., Chem. J. Chinese Universities,2018, 39(5), 1034—1040
	(严玲玲, 刘春光, 蒋梦绪. 高等学校化学学报, 2018, 39(5), 1034—1040 )
[5]	Weinstock I. A., Schreiber R. E., Neumann E., Chem.Rev.,2018, 118(5), 2680—2717
[6]	Wang B., Bi L. H., Wu L. X., J. Mater.Chem.,2011, 21(1), 69—71
[7]	Gu H. Y., Bi L. H., Fu Y., Wang N., Liu S. Q., Tang Z. Y., Chem.Sci.,2013, 4(12), 4371—4377
[8]	Zhai Y. L., Zhu Z. J., Zhu C. Z., Zhu J. B., Ren J. T., Wang E. K., Dong S. J., Nanoscale,2013, 5(10), 4344—4350
[9]	Wang Z. L., Ma Y., Zhang R. L., Peng A. D., Liao Q., Cao Z. W., Fu H. B., Yao J. N., Adv.Mater.,2009, 21(17), 1737—1741
[10]	Qin B., Chen H. Y., Liang H., Fu L., Liu X. F., Qiu X. H., Liu S. Q., Song R., Tang Z. Y., J. Am. Chem.Soc.,2010, 132(9), 2886—2888
[11]	Wang B., Yin Z. D., Bi L. H., Wu L. X., Chem.Commun.,2010, 46(38), 7163—7165
[12]	Gao W. M., Yu T., Wu L. X., Bi L. H., Chem.Commun.,2016, 52(68), 10403—10406
[13]	Gao W. M., Yu T., Du Y., Wang R. Q., Wu L. X., Bi L. H., ACS Appl. Mater.Interfaces,2016, 8(18), 11621—11628
[14]	Wang B., Meng R. Q., Bi L. H., Wu L. X., Dalton Trans.,2011, 40(19), 5298—5301
[15]	Zhai Y. L., Zhu C. Z., Ren J. T., Wang E. K., Dong S. J., Chem.Commun.,2013, 49(24), 2400—2402
[16]	Wang B., Wang X. H., Wu Y. G., Zheng J. H., Liu Z. R., Bi L. H., Wu L. X., Chinese J. Inorg.Chem.,2016, 32(6), 994—1000
	(王斌, 王晓红, 乌英嘎, 郑金慧, 刘宗瑞, 毕立华, 吴立新. 无机化学学报, 2016, 32(6), 994—1000 )
[17]	Song C. Y., Chai D. F., Zhang R. R., Liu H., Qiu Y. F., Guo H. D., Gao G. G., Dalton Trans.,2015, 44(9), 3997—4002
[18]	Arendt E., Zehri S., Eloy P., Gaigneaux E. M., Eur. J. Inorg.Chem.,2012, 2012(16), 2792—2801
[19]	Liu D., Tan H. Q., Chen W. L., Li Y. G., Wang E. B., CrystEngComm,2010, 12(7), 2044—2046
[20]	Zhang Z. M., Zhang T., Wang C., Lin Z., Long L. S., Lin W. B., J. Am. Chem.Soc.,2015, 137(9), 3197—3200
[21]	Wang B., Li B., Hou G. F., Li H. L., Wang S., Wu L. X., Walter S., Bi L. H., J. Cluster Sci.,2014, 25(3), 741—753
[22]	Yamase T., Chem.Rev., 1998, 98(1), 307—326
[23]	Ritchie C., Moore E. G., Speldrich M., Kögerler P., Angew. Chem. Int.Ed.,2010, 49(42), 7702—7705
[24]	Liu S. P., XuL., Li F. Y., Xu B. B., Sun Z. X., J. Mater.Chem.,2011, 21(6), 1946—1952
[25]	Wang Y. Z., Shi L., Yang Y., Li B., Wu L. X., Dalton Trans.,2014, 43(35), 13178—13186
[26]	Jin L. H., Fang Y. X., Wen D., Wang L., Wang E. K., Dong S. J., ACS Nano,2011, 5(6), 5249—5253

Spectral Detection for Vitamin C and H₂O₂ Based on the Reversible Color Change and Luminescent Switching Properties of P₂Mo₁₈ $O 62 6 -$ @Tb³⁺ Mixed Solution^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 26

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Taiwen, GUO Jun, ZHANG Dan, YUAN Changmei, QIU Shuangyan. Synthesis， Characterization and Catalytic Oxidation Iodine Ion Performance of trz-Cl-Cu-PMo₁₂ [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220215.
[2]	WEI Zheyu, WU Zhikang, RU Shi, NI Lubin, WEI Yongge. Research Progress of Polyoxometalates-Cyclodextrin Supramolecular System [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210665.
[3]	MA Mengmeng, QU Xiaogang. Recent Advances on Polyoxometalates as Metallodrug Agents for Alzheimer’s Disease ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 884.
[4]	CHEN Bing-Nian, FENG Zhen-Ge, WANG Li*. Antibacterial Activities of Polyoxometalates Containing Silicon [J]. Chem. J. Chinese Universities, 2011, 32(5): 1033.
[5]	LI Xin-Xiong, FANG Wei-Hui, YANG Guo-Yu*. Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H2O)3]2[Ni(Hdien)2]{[Ni(dien)]2·Ni4(H2O)2(GeW9O34)2}·10H2O [J]. Chem. J. Chinese Universities, 2011, 32(3): 571.
[6]	FU Hai, WANG Xiao-Lan, CHEN Wei-Lin, MENG Jing-Xin, LI Yang-Guang, WANG En-Bo. Based on Solvents Effect Building Novelty Polyoxometalates Supermolecule Compounds [J]. Chem. J. Chinese Universities, 2011, 32(3): 650.
[7]	SHU Xin, ZHOU Xin, PAN Qing-Jiang, LI Ming-Xia, ZHANG Hong-Xing*, ....... Theoretical Study on Electronic Properties and Stability of [Mo₆O₁₉]^2- and Tungsten Substituted Complexes Bearing Lindqvist Structure [J]. Chem. J. Chinese Universities, 2009, 30(5): 1014.
[8]	YANG Yun-Xu*, DENG Xiao-Rong, JI Xing-Yue, QIN Li-Juan, SUN Zhen. Syntheses of Two Kinds of Tosylamine Compounds and Their Fluorescence Switch Character for the Oxidation-reduction of Fe³⁺ [J]. Chem. J. Chinese Universities, 2008, 29(5): 919.
[9]	GAN Xiong^1,2, ZHANG Zhi-Ming¹, WANG En-Bo¹*. New 1D Ladder-Like Chain Polyoxometalate Consisting of the Paradodecatungstate Linked by Mn²⁺ Ions [J]. Chem. J. Chinese Universities, 2007, 28(12): 2242.
[10]	LI Zhong-Feng^1,2, LI Wei-Sheng^1,2, LIAO Pei-Qiu^1,2, WEI Lai^1,2, LI Xiao-Jing¹, JING Feng-Ying¹, PEI Feng-Kui¹, WANG Xu-Xia^2,3, LEI Hao³. Study of Two Sandwich-type Manganese Polyoxometalates as Potential MRI Contrast Agents [J]. Chem. J. Chinese Universities, 2007, 28(11): 2021.
[11]	WANG Sheng-Tian, QIN Yu-Hua, ZHAI Sheng-Yong, ZHOU Li-Heng, XU Hong-Ding, LI Jing-Hong . Electrochemical Property Study of Polyoxometalates Acid-polypyrrole Nanopaticles Glass Carbon Electrode Modified with a Macroporous Anodic Alumina Membrane [J]. Chem. J. Chinese Universities, 2004, 25(5): 841.
[12]	PENG Ge, HU Chang-Wen, WANG Yong-Hui, CHEN Li-Dong, WANG En-Bo, FENG Shou-Hua, LIU Yan-Yong . Synthesis and Oxidative Catalysis of Microporous Heteropolyoxometalates Cs_xH_5-xPW₁₀V₂O₄₀SiO₂ [J]. Chem. J. Chinese Universities, 2002, 23(3): 478.
[13]	GUO Yi-Hang, YANG Yu, HU Chang-Wen, WANG En-Bo . Preparation and Characterization of Three-dimensional Ordered Macroporous Hybrid SiW₁₁O₃₉^8--SiO₂ and γ-SiW₁₀O₃₆^8--SiO₂ Composites [J]. Chem. J. Chinese Universities, 2002, 23(11): 2035.
[14]	LIU Jian-Yun, CHENG Long, DONG Shao-Jun . Multilayer Assembly of Mn-substituted Keggin-type [ZnW₁₁O₃₉ Mn(H₂O)]^8- on Chemically Modified Glassy Carbon Electrode and Its Electrocatalytic Properties [J]. Chem. J. Chinese Universities, 2001, 22(10): 1641.
[15]	PENG Ge, HU Chang-Wen, CHEN Li-Dong, WANG En-Bo . Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO₄Al₁₂(OH)₂₄(H₂O)₁₂]^⁷⁺ and Heteropolyoxometalates [J]. Chem. J. Chinese Universities, 2001, 22(10): 1629.