Catalytic Performance Comparison of the Novel Catalyst La2CuMnO6 and LaMnO3 for Methane Combustion

Abstract

Abstract: A novel rare-earth double perovskite-type catalyst La2CuMnO6 was prepared by the sol-gel method using citric acid as a complex agent. The catalytic activity of the sample toward methane combustion was evaluated. The catalyst was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, magnetic properties, H2-temperature-programmed reduction, Scanning electron microscopy and X-ray photoelectron spectroscopy. The results show that La2CuMnO6 forms a single-phase double perovskite-type oxide by the sol-gel method at 1100 ℃ under air atmosphere for 3 h. The La2CuMnO6 reveals good catalytic activity for methane combustion. It shows light off temperature T10 of 437.5 ℃ and T90 of 649.2 ℃. Compared with the single perovskite-type oxide LaMnO3 which always was made for methane combustion catalyst, the lower light-off temperature T10 decreases 53.1 ℃ and total conversion T90 decreases 116.5 ℃, respectively. The results of FTIR show that the synthesized oxides all possess perovskite-type structures. The results of H2-TPR indicate that an increasing in the oxygen mobility existe in La2CuMnO6. Furthermore, the SEM, TEM and the magnetic properties results also testified that, the two catalysts have different surface feature and magnetic property, In addition, XPS shows that La2CuMnO6 have more oxygen vacancies than LaMnO3. These results are in the accord with methane catalytic combustion.

Key words: Rare earth, Double perovskite-type oxide, Single perovskite-type oxide, Methane catalytic combustion, Sol-gel

CLC Number:

O643

TrendMD:

CHEN Jie, HU Rui-Sheng*, HU Jia-Nan, LU Tian-Zhu. Catalytic Performance Comparison of the Novel Catalyst La2CuMnO6 and LaMnO3 for Methane Combustion[J]. Chem. J. Chinese Universities, 2011, 32(10): 2396.

References

参考文献 [1] Kobayashi K.I., Kimura T., Sawada H., Terakura K. et al.. Nature. [J] , 1998, 395: 677-680 [2] Han Hong-Mei(韩红梅), Wang Jin-Hui(王锦辉), Du You-Wei(都有为). et al.. Journal of Functional Materials《功能材料》[J] , 2001, 32(6):568-571 [3] Yun-Hui Huang, Ronald I. Dass, John B.Goodenough. et al.. Science. [J], 2006, 312: 254-257 [4] Colis S., Pourroy G., Panissod P., et al.. Journal of Magnetism and Magnetic Materials. [J] , 2004, 272–276: 2018-2020 [5] Falcon H., Barbero J.A., Fierro J.L.G. et al.. Appl. Catal. B, [J] , 2004, 53:37-45 [6] Arai H., Yamada T., Seiyama T., et al.. Appl. Catal, [J] , 1986, 26, 265-276 [7] Davide Ferri, Lucio ForniF, Appl. Catal. B, [J], 1998, 16: 119-126 [8] Fabbrini L., Kryukov A., Forni L., et al.. Journal of Catalysis, [J], 2005,232:247-256 [9] Wang Hong(王虹), Zhao Zhen(赵震), Xu Chun-ming(徐春明).et al.. Chinese Journal of Catalysis(催化学报), [J], 2008, 29(7): 649-654 [10] Zhu Yong-fa(朱永法),Tan Rui-Qin(谭瑞琴),Feng Jie(冯杰).et al.. Chem. J. Chinese Universities (高等学校化学学报) [J], 2000, 21(11): 1733-1737 [11] Shaheen R., Bashir J., Solid State Sciences , [J], 2010, 12: 1496-1499 [12] Roa-Rojas J., Salazar M. C., et al.. Journal of Magnetism and Magnetic Materials, [J] , 2008, 320: 104-106 [13] Andrey J. Zarur, Jackie Y. Ying, Nature. [J] , 2000, 403: 65-67 [14] Liu She-tian(刘社田), Yu Zuo-long(于作龙), Wu Yue(吴越), Journal of Inorganic Materials(无机材料学报), [J], 1994, 9(2): 184-190 [15] Wei Kun(魏坤), Shi Yan(石燕), Peng Shan-shan(彭珊珊). Rare Earth(稀土) [J],1998,19 (5): 33-36 [16] Li Ran-jia(李然家), Yu Chang-chun(余长春), Shen Shi-kong(沈师孔) et al.. Chinese Journal of Catalysis(催化学报), [J], 2002, 23(6) : 549-554 [17] Xu Xiu-feng(徐秀峰), Suo Zhang-huai(索掌怀), Li Da-li(李大力) et al.. Journal of Molecular Catalysis(分子催化) [J], 2001,15 (4): 259-262 [18] Chen Jing(陈静),Jin Guo-jun(金国钧), Ma Yu-qiang(马余强). Acta Physica Sinica(物理学报). [J],2009, 58(4): 2707-2711 [19] Daniel Stoef?er, Silviu Colis. Materials Science and Engineering B, [J], 2006,126:133-138

Related Articles 15

[1]	JIANG Xiaokang, ZHOU Qi, ZHOU Hengwei. Synthesis and Luminescence Properties of Gd₂ZnTiO₆∶Dy³⁺， Eu³⁺ Single Phase White Light-emitting Phosphors [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220029.
[2]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[3]	ZHOU Yonghui, LI Yao, WU Yuxuan, TIAN Jing, XU Longquan, FEI Xu. Synthesis of A Novel Photoluminescence Self-healing Hydrogel [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210606.
[4]	WEI Chuangyu, CHEN Yanli, JIANG Jianzhuang. Fabrication of Electrochemical Sensor for Dopamine and Uric Acid Based on a Novel Dimeric Phthalocyanine-involved Quintuple-decker Modified Indium Tin Oxide Electrode [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210582.
[5]	HAN Zongsu, YU Xiaoyong, MIN Hui, SHI Wei, CHENG Peng. A Rare Earth Metal-Organic Framework with H₆TTAB Ligand [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210342.
[6]	LI Yishan, GUO Liang, PENG Sifan, ZHANG Qingmao, ZHANG Yuhao, XU Shiqi. Cobalt Substitutions in Lanthanum Manganate Photocatalyst： First-principles and Visible-light Photocatalytic Ability Investigation [J]. Chem. J. Chinese Universities, 2021, 42(6): 1881.
[7]	HAN Yandong, HAN Mingyong, YANG Wensheng. Sol-gel Construction of Mesoporous Silica Nanomicrostructures [J]. Chem. J. Chinese Universities, 2021, 42(4): 965.
[8]	LIANG Longqi, CHEN Cailing, YU Ying, LI Yuxin, LI Chunguang, SHI Zhan. Synthesis, Luminescence and Cell Imaging Properties of Amino Acid Capped YVO₄∶Eu Nanoparticles ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 425.
[9]	HAN Hongjing,GE Qin,CHEN Yanguang,WANG Haiying,ZHAO Hongzhi,WANG Yizhen,ZHANG Yanan,DENG Jitong,SONG Hua,ZHANG Mei. Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of Ca₁_-xPr_xFe $O 3 †$ [J]. Chem. J. Chinese Universities, 2020, 41(2): 331.
[10]	RAN Shiya,SHEN Haifeng,LI Xiaonan,WANG Zilu,GUO Zhenghong,FANG Zhengping. Effect and Mechanism of Rare Earth Trifluoromethanesulfonate on the Thermal Stability of Polypropylene^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1333.
[11]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[12]	LIANG Donglei, SONG Qiusheng, YAO Yutian, LIU Ben. Preparation of Complex Nanogel with Up-conversion Fluorescence-responsive Performance and Its Fluorescence Energy Transfer Behavior^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 583.
[13]	ZHANG Shuming, LUO Jianhui, XIA Bibo, LI Yuanyang, HE Meiying, JIANG Bo. Sol-gel Preparation of Superhydrophilic Silica Coating-materials with Low Refractive Index^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1342.
[14]	ZHANG Yan, ZHANG Shengming, FANG Guizhen. Antioxidant Property of Catalyzed Lignosulfonate Using S₂ $O 8 2 -$ /ZrO₂ Doped Cerium as Catalysts^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1255.
[15]	TANG Keyun,LI Luoyuan,FU Limin,AI Xicheng,ZHANG Jianping. Effect of Crystal Matrix on Energy Transfer Mechanism in Rare-earth Upconversion Nanomaterials^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2136.