Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (11): 2190.

• Articles • Previous Articles     Next Articles

Effect of Agarose Properties on the Separation of m-SWCNTs and s-SWCNTs by the AGE

ZHANG Jing1,2, WEN Xiao-Nan1,2, LI Hong-Bo2, JIN He-Hua2, SONG Qi-Jun1*, LI Qing-Wen2*   

  1. 1. School of Chemistry and Material Engineering, Jiangnan University, Wuxi 214000, China;
    2. Functional Nanomaterials Group, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125, China
  • Received:2010-03-08 Online:2010-11-10 Published:2010-11-10
  • Contact: SONG Qi-Jun. E-mail: qsong@jiangnan.edu.cn; LI Qing-Wen. E-mail: qwli2007@sinano.ac.cn
  • Supported by:

    国家自然科学基金青年基金(批准号: 20903069)和科技部国际合作项目(批准号: 2009DFB50150)资助.

Abstract: The agarose gel electrophoresis(AGE) is one of the low-cost, large-scale technologies for the separation of metallic single-walled carbon nanotubes(m-SWCNTs) and semiconducting single-walled carbon nanotubes(s-SWCNTs). In this paper, AGE technique was used to investigate the influence of the properties of MB, Agarose, Agarose B and LRU on the separating efficiency of SWCNTs. By characterizing their UV-Vis-NIR absorption spectra, we found that different agarose had little influence on the separating efficiency of s-SWCNTs, and had a great effect on the separating efficiency of m-SWCNTs. Furthermore, by comparing the properties of differents agarose gel including gel strength, mesh size and so on, we consider that the major factors in separating efficiency of m-SWCNTs are the gel strength and gel mesh size. The results indicate that the smaller mesh size of the gel is favorable to the enrichment of m-SWCNTs, while the higher gel strength is unfavorable.

Key words: Single-walled carbon nanotube, Separation, Agarose gel electrophoresis(AGE), Gel strength, Mesh size

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