Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (9): 1475.

• Articles • Previous Articles     Next Articles

A Kinetic Study on the Photocatalytic Degradation of Methomyl

ZHANG Man-Ping1, ZHAN Run1, XIA Zong-Feng1, Gary Low2   

  1. 1. College of Chemistry and Chemical Engineering, Ocean University of Qingdao, Qingdao, 266003;
    2. CSIRO Division of Coal and Energy Technology, PMB 7, Bangor, NSW 2234, Australia
  • Received:1997-08-13 Online:1998-09-24 Published:1998-09-24

Abstract: The photocatalytic degradation of a wisely used pesticidemethomyl was studied in this paper. The degradation was catalyzed by titanium dioxide. The products, kinetics and factors that affect the rate of degradation was discussed. Methymol can be photooxided into inorganic materials in 10 minutes under the catalysis of titanium dioxide. FTIRstudy shows that the products are NH4+, SO42- and CO2. The degradation is first order reaction and the kinetic reaction curve was modeled. Some cations and anions can affect the reaction rate. Most ions retard the rate but Cu2+ and Cl- at low concentrations stimulate the reaction.

Key words: Methymol, Photocatalytic degradation, Kinetic study

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