Studies on Thermokinetics (XXIV)——Thermokinetics Method for the Third Order Reaction

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1440.

• Articles • Previous Articles Next Articles

Studies on Thermokinetics (XXIV)——Thermokinetics Method for the Third Order Reaction

WANG Rui-Lin, DUAN Zhi-Hua, ZENG Xian-Cheng, QIN Zi-ming, DENG Yu

Department of Chemistry, Sichuan University, Chengdu, 610064

Received:1991-12-26 Revised:1992-08-03 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: On the theoretical basis of thermokinetics proposed in the literature,the method of di-mensionless parameters for the third order reactions are derived in this paper.This method has been used to study the formation of hexamethylenetetramine in aqueous solutions at two different temperatures.The rate constants of these reactions calculated by using this method are in agreement with the values in literature.And therefore,the foundamental equations of thermokinetic method for the third order reactions are believed to be correct.

Key words: Thermokinetics, The third order reactions with the same concentration, Hexamethylenetetramine

TrendMD:

WANG Rui-Lin, DUAN Zhi-Hua, ZENG Xian-Cheng, QIN Zi-ming, DENG Yu . Studies on Thermokinetics (XXIV)——Thermokinetics Method for the Third Order Reaction[J]. Chem. J. Chinese Universities, 1992, 13(11): 1440.

[1]	WAN Ting, LI Xingxing, HUANG Zaiyin, QIU Jiangyuan, ZUO Chen, TAN Xuecai. In-situ Photocatalytic Process of Rhodamine B over g-C₃N₄@Ag₃PO₄ Nanocomposites Based on Photomicrocalorimeter-fluorescence Spectrometry^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2226.
[2]	MA Yu-Jie, FAN Gao-Chao, CHEN Jie, HUANG Zai-Yin. In situ Thermokinetic Investigation on the Growth of MnMoO₄稨₂O Nanorods [J]. Chem. J. Chinese Universities, 2012, 33(08): 1813.
[3]	QIN Fang-Fang¹, HE Ming-Zhong¹*, CUI Jing-Wei², CHEN Qiang³. Thermokinetics Study on the Deintercalation Reaction of Intercalating Composite Kaolinite/Dimethyl Sulphoxide [J]. Chem. J. Chinese Universities, 2007, 28(12): 2343.
[4]	HUANG Yu-Ping, LIU Yi, SHEN Ping, QU Song-Sheng . Thermokinetic Study on the Growth Process of Halobacterium Halobium [J]. Chem. J. Chinese Universities, 2002, 23(2): 251.
[5]	CHEN Yong, WANG Hai-Dong, LI Yan-Tuan, ZENG Xian-Cheng . Time-parameter Method(Ⅵ) Studies on Thermokinetics for Consecutive First-order Reactions [J]. Chem. J. Chinese Universities, 2001, 22(11): 1852.
[6]	CHEN Yong, JIANG Fu-Bin, XIE Jia-Qing, ZHANG Yuan-Qin, ZENG Xian-Cheng . Timeparameter Method(Ⅳ) Studies on Thermokinetics for Opposite Reaction [J]. Chem. J. Chinese Universities, 1999, 20(6): 928.
[7]	LIU Yi, TAN Xiao-Feng, WANG Cun-Xin, YAN Cheng-Nong, SONG Zhao-Hua, QU Song-Sheng  . Studies on Thermokinetic Method(Ⅱ)——Theory and Method of Flow-mixed Method [J]. Chem. J. Chinese Universities, 1998, 19(6): 938.
[8]	ZENG Xian-Cheng, CHEN Yong, WANG Qian, MENG Xiang-Guang, QIN Zi-Ming . Time Variable Method of Thermokinetics——Chemical Reactions with Simple Order [J]. Chem. J. Chinese Universities, 1998, 19(11): 1803.
[9]	ZHANG Yuan-Qin, ZENG Xian-Cheng, HU Qi-Shan, MENG Xiang-Guang, TIAN An-Min . Analog Thermogram Method(Ⅲ)──Reversible Reactions [J]. Chem. J. Chinese Universities, 1997, 18(8): 1369.
[10]	ZENG Xian-Cheng, MENG Xiang-Guang, ZHANG Yuan-Qin, CHEN Min-Zhu, QIN Zi-Ming, HU Qi-Shan. Research Method for Kinetics of Chemical Reactions ──Self-function Regression Method and Its Applications [J]. Chem. J. Chinese Universities, 1997, 18(4): 581.
[11]	LIANG Yi, WANG Cun-Xin, ZOU Guo-Lin, QU Song-Sheng, WU Yuan-Xin, LI Ding-Huo. Studies of Xanthine Oxidation by Xanthine Oxidase Using Microcalorimetry [J]. Chem. J. Chinese Universities, 1997, 18(4): 586.
[12]	ZHANG Yuan-Qin, HU Qi-Shan, ZENG Xian-Cheng, TIAN An-Min. Analog Thermogram Method(Ⅱ)──Studies on Thermokinetics of Irreversible Consecutive First-order Reactions [J]. Chem. J. Chinese Universities, 1997, 18(3): 463.
[13]	ZENG Xian-Cheng, ZHANG Yuan-Qin, MENG Xiang-Guang, CHEN Min-Zhu, QIN Zi-Ming, HU Qi-Shan. Analog Thermogram Method(Ⅰ)──Chemical Reactions with Simple Order [J]. Chem. J. Chinese Universities, 1996, 17(4): 607.
[14]	XIONG Ya, WU Ding-Quan, ZHOU Guang-Ming, DU Yu-Min, QU Song-Sheng. The Microcalorimetric Studies on the Inhibition Kinetics of Enzyme-catalyzed Reaction──Fluoride Ion Inhibiting Laccase-catalyzed Oxidation Reaction of o-Phenylenediamine [J]. Chem. J. Chinese Universities, 1996, 17(3): 460.
[15]	LIU Jing-Song, ZENG Xian-Cheng, DENG Yu, TIAN An-Min. Thermokinetic Research of Consecutive Quaternizations [J]. Chem. J. Chinese Universities, 1994, 15(8): 1207.

Studies on Thermokinetics (XXIV)——Thermokinetics Method for the Third Order Reaction

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments