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Sr2SiO4∶Dy3+材料制备及发光特性

李盼来, 杨志平, 王志军, 郭庆林   

  1. 河北大学物理科学与技术学院, 保定 071002
  • 收稿日期:2007-07-23 修回日期:1900-01-01 出版日期:2008-03-10 发布日期:2008-03-10
  • 通讯作者: 李盼来

Preparation and Luminescence Characteristics of Sr2SiO4∶Dy3+ Phosphor

LI Pan-Lai*, YANG Zhi-Ping, WANG Zhi-Jun, GUO Qing-Lin   

  1. College of Physics Science & Technology, Hebei University, Baoding 071002, China
  • Received:2007-07-23 Revised:1900-01-01 Online:2008-03-10 Published:2008-03-10
  • Contact: LI Pan-Lai

摘要: 采用高温固相法制备了Sr2SiO4∶Dy3+发光材料. 在365 nm紫外光激发下, 测得Sr2SiO4∶Dy3+材料的发射光谱为一个多峰宽谱, 主峰分别为486, 575和665 nm; 监测575 nm的发射峰, 所得材料的激发光谱为一个多峰宽谱, 主峰分别为331, 361, 371, 397, 435, 461和478 nm. 研究了Dy3+掺杂浓度对Sr2SiO4∶Dy3+材料发射光谱强度的影响. 研究结果显示, 随着Dy3+浓度的增大, 黄、蓝发射峰比值(Y/B)也逐渐增大; 随着Dy3+浓度的增大, 575 nm发射峰强度先增大后减小. 加入电荷补偿剂Li+, Na+和K+均提高了Sr2SiO4∶Dy3+材料的发射光谱强度, 其中以Li+的情况最为明显.

关键词: 白光LED, Sr2SiO4∶Dy3+, 发光特性

Abstract: The Sr2SiO4∶Dy3+ phosphor was synthesized by high temperature solid-state method. The emission spectrum of Sr2SiO4∶Dy3+ shows several bands at 486, 575 and 665 nm under the 365 nm excitation. The excitation spectrum for 575 nm emission has several excitation bands at 331, 361, 371, 397, 435, 461 and 478 nm. The effect of Dy3+ concentration on the emission spectrum intensity of Sr2SiO4∶Dy3+ was investigated, the result shows that the ratio(Y/B) of yellow emission(575 nm) to blue emission(486 nm) increases with increasing Dy3+ concentration, the 575 nm yellow emission intensity firstly increases with increasing Dy3+ concentration, then decreases. With the condition of immitting the charge compensation, the emission spectrum intensity of Sr2SiO4∶Dy3+ is enhanced, and the effect is most distinctly with immitting Li+.

Key words: White LED, Sr2SiO4∶Dy3+, Luminescence characteristics

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