高等学校化学学报

高等学校化学学报

• 研究论文 • 上一篇    下一篇

低温固相反应挤出PET/PC合金中的多重网络增韧结构

郭卫红, 王晓光, 徐东东, 张万里, 殷国蓉, 吴驰飞   

  1. 华东理工大学材料科学与工程学院高分子合金研究室, 教育部超细材料制备与应用重点实验室, 上海 200237
  • 收稿日期:2007-04-28 修回日期:1900-01-01 出版日期:2007-11-10 发布日期:2007-11-10
  • 通讯作者: 郭卫红

Multi-network Reinforced Structure of PET/PC Alloys by Low Temperature Solid-state Reactive Blend

GUO Wei-Hong*, WANG Xiao-Guang, XU Dong-Dong, ZHANG Wan-Li, YIN Guo-Rong, WU Chi-Fei   

  1. Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, Research Laboratory of Polymer Alloys, College of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Received:2007-04-28 Revised:1900-01-01 Online:2007-11-10 Published:2007-11-10
  • Contact: GUO Wei-Hong

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被引次数

21

摘要： 以聚对苯二甲酸乙二酯(PET)瓶片为主要原料, 加入聚碳酸酯(PC)、热塑性弹性体及扩链剂, 采用低温固相反应挤出制备了具有良好强度与韧性的新型合金. 在加工过程中产生PET相和PC相互穿的网络结构的同时, 反应性扩链剂在PET相中发生交联反应, 形成了次级网络结构. 由于这些网络结构的存在, 使合金材料的力学性能得到明显提高, 特别是缺口冲击性能有了明显的改善.

关键词: PET/PC合金, 低温固相加工, 反应挤出, 多重网络结构, 增韧结构

Abstract: By adding of chain extender and thermo plastic elastomer, PET/PC reactive alloys were prepared via low temperature solid-state blending. Novel toughening alloy is gained with outstanding mechanical properties and thermal properties. The structures of PET/PC alloys were studied and the multiple network which was formed by this processing greatly reinforced the alloy.

Key words: PET/PC alloy, Low temperature solid-state processing, Reactive blend, Multi-network, Reinforced structure

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