高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 255.

• Chemistry in Materials Sciences • 上一篇    下一篇

Syntheses and Structures of (Ga1-xBx)PO4, with a New Modification of High Cristobalite, and (B1-xZnx)PO4, with Low Cristobalite Type

MI J.-X., HUANG Y.-X., MAO S.-Y., JIANG Y.-Q., ZHOU Z.-H., ZHAO J.-T.   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 通讯作者: ZHAO J.-T.
  • 基金资助:

    Project supported by NNSF of China, Foundation for University Key Teacher by Ministry of Education and NSF of Fujian Province.

Syntheses and Structures of (Ga1-xBx)PO4, with a New Modification of High Cristobalite, and (B1-xZnx)PO4, with Low Cristobalite Type

MI J.-X., HUANG Y.-X., MAO S.-Y., JIANG Y.-Q., ZHOU Z.-H., ZHAO J.-T.   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
  • Online:2000-12-31 Published:2000-12-31
  • Contact: ZHAO J.-T.
  • Supported by:

    Project supported by NNSF of China, Foundation for University Key Teacher by Ministry of Education and NSF of Fujian Province.

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摘要：

The transition metal element substitutions of the industrial catalytic material ortho-borophosphate, BPO4, can lead to either new type of structure for Cr[1] or stabilize low cristobalite structure for Mn, Fe,Co, Ni and Cu[2] Here we report our results on the substitution by main group elements Zn and Ga. The two title compounds were synthesized by high temperature solid state reactions and the structure were refined by powder diffraction methods.The structure parameters:(B0.25Ga0.75)PO4:Tetragonal, P-4, a=4.727(1), c=7.078(1) Å,V=158.17(1) Å3, Z=2, R(P)=0.0965, R(I)=0.0426; (B0.61Zn0.39)PO4:Orthorhombic, C2221 a=7.080(1), b=7.087(1),c=6.990(1) Å, V=350.71(2) Å3, Z=4,R(P)=0.0904,R(I)=0.0438. Pure GaPO4 were found three kinds of structures, low- and high-cristobalite and high -quartz with an observation of an unknown unstable high cristobalite at high temperature[3] The boron substitution of the high-cristobalite GaPO4 with space group I-A leads to lower symmetry space group(P-4). We assume the low symmetry structure related to the unknown unstable phase. The structures of both compounds are similar to very well known cristobalite (see figure below).

Abstract:

The transition metal element substitutions of the industrial catalytic material ortho-borophosphate, BPO4, can lead to either new type of structure for Cr[1] or stabilize low cristobalite structure for Mn, Fe,Co, Ni and Cu[2] Here we report our results on the substitution by main group elements Zn and Ga. The two title compounds were synthesized by high temperature solid state reactions and the structure were refined by powder diffraction methods.The structure parameters:(B0.25Ga0.75)PO4:Tetragonal, P-4, a=4.727(1), c=7.078(1) Å,V=158.17(1) Å3, Z=2, R(P)=0.0965, R(I)=0.0426; (B0.61Zn0.39)PO4:Orthorhombic, C2221 a=7.080(1), b=7.087(1),c=6.990(1) Å, V=350.71(2) Å3, Z=4,R(P)=0.0904,R(I)=0.0438. Pure GaPO4 were found three kinds of structures, low- and high-cristobalite and high -quartz with an observation of an unknown unstable high cristobalite at high temperature[3] The boron substitution of the high-cristobalite GaPO4 with space group I-A leads to lower symmetry space group(P-4). We assume the low symmetry structure related to the unknown unstable phase. The structures of both compounds are similar to very well known cristobalite (see figure below).

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